The rate constant k for a certain reaction is measured at two different temperatures: temperature k 330.0 °C 6.1 × 10 ¹0 442.0 °C 3.7 x 10¹¹ Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ E x10 mol X 3 ?

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### Calculating Activation Energy using the Arrhenius Equation

The rate constant, \(k\), for a certain reaction is measured at two different temperatures:

| **Temperature** | \( k \)          |
|-----------------|------------------|
| 330.0 °C        | \( 6.1 \times 10^{10} \) s\(^{-1}\) |
| 442.0 °C        | \( 3.7 \times 10^{11} \) s\(^{-1}\) |

Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction. Round your answer to 2 significant digits.

### Key Concepts:
1. **Arrhenius Equation**: The Arrhenius equation is given by:

\[ k = A e^{-\frac{E_a}{RT}} \]

where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor (frequency factor),
- \( E_a \) is the activation energy,
- \( R \) is the universal gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.

2. **Linear Form of Arrhenius Equation**: By taking the natural logarithm of both sides, the equation can be transformed into a linear form:

\[ \ln(k) = \ln(A) - \frac{E_a}{R} \frac{1}{T} \]

From here, the activation energy \( E_a \) can be determined by measuring the rate constants at different temperatures and creating a plot of \( \ln(k) \) versus \( \frac{1}{T} \). The slope of this line will be \( -\frac{E_a}{R} \).

### Step-by-Step Solution:

1. **Convert Temperatures to Kelvin**:
   \[
   T_1 = 330.0 + 273.15 = 603.15 \text{ K}
   \]
   \[
   T_2 = 442.0 + 273.15 = 715.15 \text{ K}
   \]

2. **Calculate \(\ln(k)\)**:
   \[
   \ln(k_1) = \ln(6.1 \times 10^{10}) = 24.83
   \]
   \[
   \ln(k
Transcribed Image Text:### Calculating Activation Energy using the Arrhenius Equation The rate constant, \(k\), for a certain reaction is measured at two different temperatures: | **Temperature** | \( k \) | |-----------------|------------------| | 330.0 °C | \( 6.1 \times 10^{10} \) s\(^{-1}\) | | 442.0 °C | \( 3.7 \times 10^{11} \) s\(^{-1}\) | Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction. Round your answer to 2 significant digits. ### Key Concepts: 1. **Arrhenius Equation**: The Arrhenius equation is given by: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) is the rate constant, - \( A \) is the pre-exponential factor (frequency factor), - \( E_a \) is the activation energy, - \( R \) is the universal gas constant (8.314 J/mol·K), - \( T \) is the temperature in Kelvin. 2. **Linear Form of Arrhenius Equation**: By taking the natural logarithm of both sides, the equation can be transformed into a linear form: \[ \ln(k) = \ln(A) - \frac{E_a}{R} \frac{1}{T} \] From here, the activation energy \( E_a \) can be determined by measuring the rate constants at different temperatures and creating a plot of \( \ln(k) \) versus \( \frac{1}{T} \). The slope of this line will be \( -\frac{E_a}{R} \). ### Step-by-Step Solution: 1. **Convert Temperatures to Kelvin**: \[ T_1 = 330.0 + 273.15 = 603.15 \text{ K} \] \[ T_2 = 442.0 + 273.15 = 715.15 \text{ K} \] 2. **Calculate \(\ln(k)\)**: \[ \ln(k_1) = \ln(6.1 \times 10^{10}) = 24.83 \] \[ \ln(k
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