The rate constant k for a certain reaction is measured at two different temperatures: temperature k 330.0 °C 6.1 × 10 ¹0 442.0 °C 3.7 x 10¹¹ Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ E x10 mol X 3 ?
The rate constant k for a certain reaction is measured at two different temperatures: temperature k 330.0 °C 6.1 × 10 ¹0 442.0 °C 3.7 x 10¹¹ Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ E x10 mol X 3 ?
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![### Calculating Activation Energy using the Arrhenius Equation
The rate constant, \(k\), for a certain reaction is measured at two different temperatures:
| **Temperature** | \( k \) |
|-----------------|------------------|
| 330.0 °C | \( 6.1 \times 10^{10} \) s\(^{-1}\) |
| 442.0 °C | \( 3.7 \times 10^{11} \) s\(^{-1}\) |
Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction. Round your answer to 2 significant digits.
### Key Concepts:
1. **Arrhenius Equation**: The Arrhenius equation is given by:
\[ k = A e^{-\frac{E_a}{RT}} \]
where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor (frequency factor),
- \( E_a \) is the activation energy,
- \( R \) is the universal gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.
2. **Linear Form of Arrhenius Equation**: By taking the natural logarithm of both sides, the equation can be transformed into a linear form:
\[ \ln(k) = \ln(A) - \frac{E_a}{R} \frac{1}{T} \]
From here, the activation energy \( E_a \) can be determined by measuring the rate constants at different temperatures and creating a plot of \( \ln(k) \) versus \( \frac{1}{T} \). The slope of this line will be \( -\frac{E_a}{R} \).
### Step-by-Step Solution:
1. **Convert Temperatures to Kelvin**:
\[
T_1 = 330.0 + 273.15 = 603.15 \text{ K}
\]
\[
T_2 = 442.0 + 273.15 = 715.15 \text{ K}
\]
2. **Calculate \(\ln(k)\)**:
\[
\ln(k_1) = \ln(6.1 \times 10^{10}) = 24.83
\]
\[
\ln(k](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9838a9f9-7895-4b37-8273-0eee4d7fe4f1%2F2b7a73da-48ed-44f7-99d5-73469818bf5c%2Fdbifmt9_processed.png&w=3840&q=75)
Transcribed Image Text:### Calculating Activation Energy using the Arrhenius Equation
The rate constant, \(k\), for a certain reaction is measured at two different temperatures:
| **Temperature** | \( k \) |
|-----------------|------------------|
| 330.0 °C | \( 6.1 \times 10^{10} \) s\(^{-1}\) |
| 442.0 °C | \( 3.7 \times 10^{11} \) s\(^{-1}\) |
Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction. Round your answer to 2 significant digits.
### Key Concepts:
1. **Arrhenius Equation**: The Arrhenius equation is given by:
\[ k = A e^{-\frac{E_a}{RT}} \]
where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor (frequency factor),
- \( E_a \) is the activation energy,
- \( R \) is the universal gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.
2. **Linear Form of Arrhenius Equation**: By taking the natural logarithm of both sides, the equation can be transformed into a linear form:
\[ \ln(k) = \ln(A) - \frac{E_a}{R} \frac{1}{T} \]
From here, the activation energy \( E_a \) can be determined by measuring the rate constants at different temperatures and creating a plot of \( \ln(k) \) versus \( \frac{1}{T} \). The slope of this line will be \( -\frac{E_a}{R} \).
### Step-by-Step Solution:
1. **Convert Temperatures to Kelvin**:
\[
T_1 = 330.0 + 273.15 = 603.15 \text{ K}
\]
\[
T_2 = 442.0 + 273.15 = 715.15 \text{ K}
\]
2. **Calculate \(\ln(k)\)**:
\[
\ln(k_1) = \ln(6.1 \times 10^{10}) = 24.83
\]
\[
\ln(k
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