The rate constant for the reaction H + O2 → OH + O is 4.7 x 10-7 M-1s 1 at 1000 K and the activation energy is 66.5 kJ/mol. a. Calculate the rate constant at 2000 K. b. Could the concentration vs. time data plotted below correspond to the above reaction? Why or why not? Note that this is the same set of concentration vs. time data plotted in three different ways. [A] vs time In[A] vs time 1/[A] vs time 0.20 50 -2.0 40 0.15 In[A] [A]. -3.0 mol -4.0 0.05 10 0.00 -5.0 100 200 Time. sec. 300 100 200 300 100 200 Time. sec Time. sec.

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Chapter1: Chemical Foundations
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The rate constant for the reaction
→ OH + O is 4.7 x 10-7 M-1s°
at 1000 K and the activation energy is 66.5
H + O2
1
kJ/mol.
a. Calculate the rate constant at 2000 K.
b. Could the concentration vs. time data plotted
below correspond to the above reaction? Why
or why not? Note that this is the same set of
concentration vs. time data plotted in three
different ways.
[A] vs time
In[A] vs time
1/ [A] vs time
0.20
50
-2.0
40
0.15
In[A]
[A).
-3.0
mol
(A]
-4.0
0.05
10
0.00
-5.0
200
Time. sec
100
200
Time. sec.
300
100
200
300
300
Time. sec.
Transcribed Image Text:The rate constant for the reaction → OH + O is 4.7 x 10-7 M-1s° at 1000 K and the activation energy is 66.5 H + O2 1 kJ/mol. a. Calculate the rate constant at 2000 K. b. Could the concentration vs. time data plotted below correspond to the above reaction? Why or why not? Note that this is the same set of concentration vs. time data plotted in three different ways. [A] vs time In[A] vs time 1/ [A] vs time 0.20 50 -2.0 40 0.15 In[A] [A). -3.0 mol (A] -4.0 0.05 10 0.00 -5.0 200 Time. sec 100 200 Time. sec. 300 100 200 300 300 Time. sec.
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