The –OH, -OR, -NH2 groups cannot be substituted directly by electrophilic substitution on the aromatic ring, but can be done by substitution of a diazonium group. Design the synthesis of p-nitro aniline compounds

The –OH, -OR, -NH2 groups cannot be substituted directly by electrophilic substitution on the aromatic ring, but can be done by substitution of a diazonium group. Design the synthesis of p-nitro aniline compounds

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter19: Eas: Electrophilic Aromatic Substitution

Section: Chapter Questions

Problem 7E: When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2)...

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Aldehydes and Ketones

Aldehydes and ketones are organic compounds that have a carbonyl group, C = O, as their functional group. They both differ in the placement of this carbonyl group in their structures.

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In an electrophilic aromatic substitution, which group is more activating: -COH or -CH2-CH3? Explain the reason.
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When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2) groups are substituted for hydrogens at the 2, 4 and 6 positions on the ring (the next section discusses why the 2, 4, and 6 positions are substituted). The product is a highly explosive substance called 2,4,6-trinitrotoluene. This subastance is commonly known by a three letter name. What is it?