The normalized 1s wavefunction (n = 1, l = 0) of any one-electron atom or ion can be written as Z3 5 πα 3 where Z is the nuclear charge (number of protons) and a = 100 (r, 0, 0) = R₁0(r)YO (0, ¢) = e -Zr/ao €0h² лm₂е² is the Bohr radius. (a) Construct an integral expression, in r, 0, and that can be used to determine the expectation value for the hydrogen atom potential energy, (V), and evaluate the integrals over and . Be mindful of the integration volume element.
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- In the early 1900s the normal Zeeman effect was useful to determine the electron’s e/m if Planck’s constant was assumed known. Calcium is an element that exhibits the normal Zeeman effect. The difference between adjacent components of the spectral lines is observed to be 0.0168 nm for = λ 422.7 nm when calcium is placed in a magnetic fi eld of 2.00 T. From these data calculate the value of eh/m and compare with the accepted value today. Calculate e/m using this experimental result along with the known value of h.Using Bohr's model, calculate the radius of the stable electron orbit with main quantum number 1 for the Lithium atom (Z=3). Provide your answer in Angstrom.(a) The current i due to a charge q moving in a circle with frequency frev is qfrev · Find the current due to the electron in the first Bohr orbit. (b) The magnetic moment of a current loop is iA, where A is the area of the loop. Find the magnetic moment of the electron in the first Bohr orbit in units Am2 . This magnetic moment is called a Bohr magneton.
- (a) How much energy is required to cause an electron in hydrogen to move from the n = 2 state to the n = 5 state? in J(b) Suppose the atom gains this energy through collisions among hydrogen atoms at a high temperature. At what temperature would the average atomic kinetic energy 3/2 * kBT be great enough to excite the electron? Here kB is Boltzmann's constant. in KCompute the oscillation frequency of the electron and the expected absorption or emission wavelength in a Thomson- model hydrogen atom. Use R = 0.053 nm.What is the energy in eV and wavelength in μm of a photon that, when absorbed by a hydrogen atom, could cause a transition from the n = 5 to the n = 8 energy level? HINT (a) energy in eV eV (b) wavelength in um um
- Consider an electron in the ground state of a Hydrogen atom: a) Find () and (²) in terms of the Bohr radius a0. b) Find (-) for state n = 2, 1 = 1 and m = 1 considering that x = r cos 0 sin ø.Zirconium (Z = 40) has two electrons in an incomplete d subshell. (a) What are the values of n and ℓ for each electron? n = ℓ = (b) What are all possible values of m and ms? m = − to + ms = ± (c) What is the electron configuration in the ground state of zirconium? (Use the first space for entering the shorthand element of the filled inner shells, then use the remaining for the outer-shell electrons. Ex: for Manganese you would enter [Ar]3d54s2)The first five energy levels of the hydrogen atom are at n = 1, − 13.6 eV; n = 2, − 3.4 eV;n = 3, − 1.51 eV; n = 4, − 0.85 eV; n = 5, − 0.54 eV. A hydrogen discharge lamp givesan infrared spectrum that includes a sharp line at a wavelength of 4 µm, coming from electronsexcited by the discharge to a higher level, and then jump down to a lower level. Determine theenergy lost by these electrons, and identify the higher and lower levels involved.
- An electron is in a 3p state in the hydrogen atom, given that the expectation value is 12.5a_0 What is the probability of finding the electron within +/- a_0 of your expectation value. (That is, in the range (r − a_0) < r < (r+a_0) where r is the expectation value from above. The answer should be 0.1991.ground state wave function of Hydrogen (with l=m=0), calculate the electron’s average distance from the proton in terms of the Bohr radius, a ∼0.5 ×10−10m.1) A wave function for an excited state of the hydrogen atom is given by 2 1 = sh Απαβ sin? @ exp (-i2ф). 3ao exp Зао Apply the angular momentum operators 1 Î? = - h? sin 0 - ih- + = - sin 0 d0 sin? 0 dp² to find:- i) the value of the orbital angular momentum quantum number, 1. ii) the quantum number for the z-component on the orbital angular momentum, mj.