The wave function of a hydrogen atom is in an excited state is:-1/2W221 = ( m6°)"2 (r/9a) exp(-r/3ao) sin0 cose e“.(a) What is the most probable value of r in this state? How does it relate to the Bohr modelprediction for the radius?(b) What is the magnitude of the orbital angular momentum in this state? How does it compare withthe Bohr model prediction?(c) Find the orientation of the orbital angular momentum in this state.(d) What is the shortest wavelength photon that the atom can emit making an allowed transition?Identify the terminal state (in Whilm form) and justify why the transition is allowed,

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Answered: The wave function of a hydrogen atom is…

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Please answer (i), (v), and (vi). Thank you! (i) Using Bohr model for atomic hydrogen, obtain energy levels for the 2s, 3s and 3p states in the actual number with the unit of [eV]. We consider a transition that electron in the 3p state emits a photon and make a transition to the 2s state. What is the frequency v of this photon ? (ii) Now we do not include electron spin angular momentum, and just estimate an effect of a magnetic field B on this transition (Normal Zeeman effect) with orbital angular momentum. How many lines of optical transition do we expect ? What is the interval of the frequency in the field B = 0.1 Tesla ? (iii) In this situation, we do not expect transition from 3s to 2s state if the electron is initially in the 3s state, Explain the reason. (iv) We now consider an effect of magnetic field B to a free electron spin (not in Hydrogen, but a free electron). The magnetic field of B = 1.0 Tesla will split the energy level into two (Zeeman) levels. Obtain the level…
(d) The following orbital belongs to the 3d subshell of the Hydrogen atom: r Y(r, 0, 0) = A(Z) θ, φ) 2 r e 3ao sin² (0) e²i зао where A and ao are constants. Using the operator for the z-component of orbital angular momentum (L₂ = -ih d/do) determine the m, for this particular orbital. (e) Consider the wavefunction, r r Y(r,0,0) = A-e 2do cos(0) do (i) Identify the radial part of this orbital function and the number of radial nodes. (ii) Identify the angular part of the orbital function and the number of angular nodes. Z (iii) Using this information and the L₂ = -ih d/do operator obtain the n, 1, and, m quantum numbers and identify the orbital.