The molar heat of vaporization of substance X at its normal boiling point -185.85 °C is 6.53 kJ mol¹. Calculate the internal energy, enthalpy, and entropy changes for 1 mol of X heated from-192 °C to -150 °C at 1 atm. Assume that Cp,m=75.3 +0.292T/K (JK¹ mol¹) is constant over the temperature range.

The molar heat of vaporization of substance X at its normal boiling point -185.85 °C is 6.53 kJ mol¹. Calculate the internal energy, enthalpy, and entropy changes for 1 mol of X heated from-192 °C to -150 °C at 1 atm. Assume that Cp,m=75.3 +0.292T/K (JK¹ mol¹) is constant over the temperature range.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Assume you are interested in exploring the use of ammonium nitrate (NH4NO3) as the active ingredient in an inexpensive home-made cold pack. You decide that a practical cold pack should be able to depress the temperature of 1 kg of human muscle tissue by 5 oC. Now you need to know the amount of NH4NO3 required to achieve this. Ammonium nitrate is a highly water soluble solid. You believe the enthalpy of dissolution for NH4NO3 must be determined. To this end, you add 2.339 g of NH4NO3 to 99.7 mL of water at 23.7 °C in a constant-pressure calorimeter and close the calorimeter. The temperature of the water decreases to a minimum of 21.9 °C 1) The specific heat of human muscle tissue (smuscle) is 3.47 kJ/kg oC. Given this value, how many grams of ammonium nitrate (NH4NO3) is required to depress the temperature of 1.00 kg of human muscle by 5.00 oC? Please remember, show all work in a legible, highly organized manner
Calculate the enthalpy of vaporization of SO2 at –25°C if the same at its boiling point (i.e. –10°C) be 5950 cal mol–1. Given for SO2, molar heat capacities in liquid and vapor phase are 206 cal K–1 mol–1 and 9.3 cal K–1 mol–1 respectively.
Which of the following is the standard free energy of formation (AG:) for the substance? S(g) + O2(g) → SO2(g) C(s, graphite) + 2H2(g) → CHA(g) NH3(g) → ½N2(g) +1.5H2(g) 2C(s, diamond) + 2H2(g) + O2(g) →CH3COOH (I)
The reduction of iron(III) oxide (Fe2O3) to pure iron during the first step of steelmaking, 2 FeO3(s) 4Fe(s) + 302(g) is driven by the high-temperature combustion of coke, a purified form of coal: C(s) + O2(g) → CO₂ (g) -> 11 ✓12 Suppose at the temperature of a blast furnace the Gibbs free energies of formation AG, of CO2 and Fe2O3 are -447. kJ/mol and -818. kJ/mol, respectively. Calculate the minimum mass of coke needed to produce 7800. kg of pure iron. Round your answer to 2 significant digits. kg 5
The heat of fusion ΔHf of dichloromethane CH2Cl2 is 6.2 /kJmol. Calculate the change in entropy ΔS when 796.g of dichloromethane melts at −95.1°C.
Can you help me out with this one please. Thank you.
In vacuum distillation, the surrounding pressure inside a chamber is lowered so the solvent boils at a lower temperature. This is useful when isolating compounds that are temperature-sensitive. To what pressure must a chamber be reduced to distill methanol (ΔvapH = 38.56 kJ/mol, TBP = 351 K) at 25.0°C?
1.1 mole of O₂ (g) and 2.2 moles of N₂ (g) are spontaneously mixed in a cylinder (volume = 30.0 L) with a movable piston. Assume both gases are ideal. (a) Explain why the mixing of O₂ and N₂ gases is spontaneous in term of chemical potential. (b) Calculate the final pressure (in N m2) of mixture when (i) the mixing occurs isothermally at 298 K; (ii) the initial temperatures of O₂ (g) and N₂ (g) are 306 K and 367 K, respectively, and after mixing, the temperature is equilibrated. State any assumption(s) in your calculations. (c) ) Now, the mixture in (b)(ii) is expanded isothermally and the external pressure is suddenly decreased to a final pressure of 890 Torr, determine whether the process is reversible or not.
Use the following data to determine the AH° for the conversion of diamond into graphite: C(s,diamond) +O2(g) CO,(g) AH°= -395.4 kJ 200,(g) 2c0(g) +0,(g) AH°= 566.0 kJ 2c0(g) C(s,graphite) + CO,(g) AH°= -172.5 kJ C(s,diamond) AH° = → C(s,graphite) kJ
The vaporisation of a certain element at 25.0 oC has the following enthalpy and entropy values: Hvap = 1.00 kJ mol-1 and Svap = 156 J K-1 mol-1. What is the total entropy change (Stot) for the vaporisation of this element, in J K-1mol-1?
using a calibrated solution calorimeter measured a temperature decrease of 1.10 K when 1.00 g of KNO3 was added to 74.40 g of deionized water in the calorimeter. The specific heat capacity of the solution calorimeter was found to be 4.15 J/gK. Calculate the experimental value of the molar heat of solution of KNO3, ΔHsoln. Was the dissolution of this salt exothermic or endothermic?
Determine the boiling point of CS2, in °C, from the following data: CS2(g) CS2(l) ΔHf° / (kJ mol–1) 115.3 87.9 S° / (J mol–1 K–1) 237.8 151.0 Answer Options: 258 -14 116 78 43