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The ΔH°soln of HNO3 is –33.3 kJ/mol. 11.0 mL of 14.0 M HNO3 is dissolved in 100.0 mL of distilled water initially at 25°C. How much ice at 0°C [cP = 37.1 J/(mol ·°C), ΔH°fus = 6.01 kJ/mol] must be added to return the solution temperature to 25°C after dissolution of the acid and equilibrium with the ice is reached? The molar heat capacity is 80.8 J/(mol·°C) for the solution, and the molar heat capacity is 75.3 J/(mol·°C) for pure water.

The ΔH°soln of HNO3 is –33.3 kJ/mol. 11.0 mL of 14.0 M HNO3 is dissolved in 100.0 mL of distilled water initially at 25°C. How much ice at 0°C [cP = 37.1 J/(mol ·°C), ΔH°fus = 6.01 kJ/mol] must be added to return the solution temperature to 25°C after dissolution of the acid and equilibrium with the ice is reached? The molar heat capacity is 80.8 J/(mol·°C) for the solution, and the molar heat capacity is 75.3 J/(mol·°C) for pure water.

Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.53QE
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The ΔH°soln of HNO3 is –33.3 kJ/mol. 11.0 mL of 14.0 M HNO3 is dissolved in 100.0 mL of distilled water initially at 25°C. How much ice at 0°C [cP = 37.1 J/(mol ·°C), ΔH°fus = 6.01 kJ/mol] must be added to return the solution temperature to 25°C after dissolution of the acid and equilibrium with the ice is reached? The molar heat capacity is 80.8 J/(mol·°C) for the solution, and the molar heat capacity is 75.3 J/(mol·°C) for pure water.
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