11. Chemical potential (u) is a molar Gibbs free energy (Gm). Consider the following graphs: (a) has increase in melting point at higher pressure while (b) has decrease in melting point at higher pressure. It's because the molar volume of solid is smaller than liquid in (a), while it's the opposite in (b). Explain why this happens using the properties of chemical potential, molar Gibbs free energy. Chemical potential, μ High pressure Low pressure Solid Liquid High pressure Solid Low pressure Li
11. Chemical potential (u) is a molar Gibbs free energy (Gm). Consider the following graphs: (a) has increase in melting point at higher pressure while (b) has decrease in melting point at higher pressure. It's because the molar volume of solid is smaller than liquid in (a), while it's the opposite in (b). Explain why this happens using the properties of chemical potential, molar Gibbs free energy. Chemical potential, μ High pressure Low pressure Solid Liquid High pressure Solid Low pressure Li
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:11. Chemical potential (u) is a molar Gibbs free energy (Gm). Consider the following graphs:
(a) has increase in melting point at higher
pressure while (b) has decrease in melting
point at higher pressure. It's because the
molar volume of solid is smaller than liquid
in (a), while it's the opposite in (b).
Explain why this happens using the
properties of chemical potential, molar
Gibbs free energy.
Chemical potential, μ
High
pressure
Low
pressure
(a)
Solid
Liquid
Temperature, T
High
pressure
Solid
Low
pressure
(b)
Liquid
T←
Temperature, T
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