The molar conductivities at infinite dilution of aqueous solutions of NH4Cl, NaCl, and NaOH are, respectively, 130, 108.6, and 216.5 S cm2 mol-1 at 18°C. The specific conductivity of a 0.01 M solution of ammonia at the same temperature is 9.6 x 10-5 [S cm-1] and the ion product of water is 0.59 x 1014. Determine: • The concentration of NH4+ ions in the ammonia solution. • The pH of the ammonia solution

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter10: Effect Of Electrolytes On Chemical Equilibria
Section: Chapter Questions
Problem 10.8QAP
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The molar conductivities at infinite dilution of aqueous solutions of NH4Cl, NaCl, and NaOH are, respectively, 130, 108.6, and 216.5 S cm2 mol-1 at 18°C. The specific conductivity of a 0.01 M solution of ammonia at the same temperature is 9.6 x 10-5 [S cm-1] and the ion product of water is 0.59 x 1014. Determine:

• The concentration of NH4+ ions in the ammonia solution.

• The pH of the ammonia solution.

 

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