The freezing point of water is 0.00°C at 1 atmosphere. How many grams of ammonium chloride (53.50 g/mol), must be dissolved in 211.0 grams of water to reduce the freezing point by 0.500°C ? Refer to the table for the necessary boiling or freezing point constant. Solvent Formula K, (°C/m) K¢(°C/m) Water H2O 0.512 1.86 Ethanol CH;CH,OH 1.22 1.99 Chloroform CHCI3 3.67 Benzene 2.53 5.12 Diethyl ether CH3CH,OCH,CH3 2.02 g ammonium chloride.

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**Cryoscopic Constant and Freezing Point Depression**

*The freezing point of water is 0.00°C at 1 atmosphere.*

**Problem Statement:**

How many grams of ammonium chloride (53.50 g/mol) must be dissolved in 211.0 grams of water to reduce the freezing point by 0.500°C? Refer to the table for the necessary boiling or freezing point constant.

**Solvent Properties:**

| Solvent         | Formula            | \( K_b \) (°C/m) | \( K_f \) (°C/m) |
|-----------------|--------------------|------------------|------------------|
| Water           | H\(_2\)O           | 0.512            | 1.86             |
| Ethanol         | CH\(_3\)CH\(_2\)OH | 1.22             | 1.99             |
| Chloroform      | CHCl\(_3\)         | 3.67             | -                |
| Benzene         | C\(_6\)H\(_6\)     | 2.53             | 5.12             |
| Diethyl ether   | CH\(_3\)CH\(_2\)OCH\(_2\)CH\(_3\) | 2.02 | - |

___

**Calculation to be done:**

\[ \_\_\_\_\_\_\_\, \text{g ammonium chloride} \]

**Explanation:**

To solve this problem, we will use the concept of freezing point depression. According to the formula:

\[ \Delta T_f = K_f \cdot m \]

where:
- \( \Delta T_f \) is the decrease in freezing point (0.500°C),
- \( K_f \) is the cryoscopic constant of water (1.86°C kg/mol),
- \( m \) is the molality of the solution.

Next, we find the molality (\(m\)) using:

\[ m = \frac{\Delta T_f}{K_f} \]

Then molality is converted to grams of solute using:

\[ \text{grams of solute} = m \cdot \text{molar mass of solute} \cdot \text{kg of solvent} \]

**Steps Involved:**

1. Calculate the molality \(m\).
2. Convert
Transcribed Image Text:**Cryoscopic Constant and Freezing Point Depression** *The freezing point of water is 0.00°C at 1 atmosphere.* **Problem Statement:** How many grams of ammonium chloride (53.50 g/mol) must be dissolved in 211.0 grams of water to reduce the freezing point by 0.500°C? Refer to the table for the necessary boiling or freezing point constant. **Solvent Properties:** | Solvent | Formula | \( K_b \) (°C/m) | \( K_f \) (°C/m) | |-----------------|--------------------|------------------|------------------| | Water | H\(_2\)O | 0.512 | 1.86 | | Ethanol | CH\(_3\)CH\(_2\)OH | 1.22 | 1.99 | | Chloroform | CHCl\(_3\) | 3.67 | - | | Benzene | C\(_6\)H\(_6\) | 2.53 | 5.12 | | Diethyl ether | CH\(_3\)CH\(_2\)OCH\(_2\)CH\(_3\) | 2.02 | - | ___ **Calculation to be done:** \[ \_\_\_\_\_\_\_\, \text{g ammonium chloride} \] **Explanation:** To solve this problem, we will use the concept of freezing point depression. According to the formula: \[ \Delta T_f = K_f \cdot m \] where: - \( \Delta T_f \) is the decrease in freezing point (0.500°C), - \( K_f \) is the cryoscopic constant of water (1.86°C kg/mol), - \( m \) is the molality of the solution. Next, we find the molality (\(m\)) using: \[ m = \frac{\Delta T_f}{K_f} \] Then molality is converted to grams of solute using: \[ \text{grams of solute} = m \cdot \text{molar mass of solute} \cdot \text{kg of solvent} \] **Steps Involved:** 1. Calculate the molality \(m\). 2. Convert
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