The four lowest electronic levels of a Ti atom are 3F2, 3F3, 3F4, and 5F1, at 0, 170, 387, and 6557 cm−1, respectively. There are many other electronic states at higher energies. The boiling point of titanium is 3287 °C. What are the relative populations of these levels at the boiling point? Hint: The degeneracies of the levels are 2J + 1.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter2: The First Law Of Thermodynamics
Section: Chapter Questions
Problem 2.9E
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The four lowest electronic levels of a Ti atom are 3F2, 3F3, 3F4, and 5F1, at 0, 170, 387, and 6557 cm−1, respectively. There are many other electronic states at higher energies. The boiling point of titanium is 3287 °C. What are the relative populations of these levels at the boiling point? Hint: The degeneracies of the levels are 2J + 1.

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