The following reactions take place in a batch reactor: A+B--> C (desired product) B+C-->D (hazardous product) As the reaction proceeds, D builds up in the reactor and could cause an explosion if its concentration exceeds 15 mol/L. To ensure the safety of the plant personnel, the reaction is quenched (e.g., by cooling the reactor contents to a low temperature) and the products are extracted when the concentration of D reaches 10mol/L. The concentration of C is measured in real-time, and samples are periodically taken and analyzed to determine the concentration of D. The data are shown below: Cc (mol/L) Cd (mol/L) 2.8 1.4 10 2.27 20 2.95 40 3.84 70 4.74 110 5.63 160 6.49 220 7.32 (a) What would be the general form of an expression for Cd as a function of Cc? (b) Derive the expression. (c) At what concentration of C is the reactor stopped?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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The following reactions take place in a batch reactor:

A+B--> C (desired product)

B+C-->D (hazardous product)

As the reaction proceeds, D builds up in the reactor and could cause an explosion if its concentration exceeds 15 mol/L. To ensure the safety of the plant personnel, the reaction is quenched (e.g., by cooling the reactor contents to a low temperature) and the products are extracted when the concentration of D reaches 10mol/L.

The concentration of C is measured in real-time, and samples are periodically taken and analyzed to determine the concentration of D. The data are shown below:

Cc (mol/L) Cd (mol/L)
2.8 1.4
10 2.27
20 2.95
40 3.84
70 4.74
110 5.63
160 6.49
220 7.32

(a) What would be the general form of an expression for Cd as a function of Cc?

(b) Derive the expression.

(c) At what concentration of C is the reactor stopped?

(d) Someone proposed not stopping the reaction until Cd=13 mol/L, and someone else strongly objected. What would be the major arguements for and against that proposal?

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