The following mechanism has been proposed for the conversion of tert-butyl bromide to tert-butyl alcohol in aqueous solution: step 1 slow: (CH)3CB (CH3)3C* + Br step 2 fast: (CH3)3C* + OH° → (CH)¿COH (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]"[B]"., where '1' is understood (so don't write it) for m, n etc.) Rate =
The following mechanism has been proposed for the conversion of tert-butyl bromide to tert-butyl alcohol in aqueous solution: step 1 slow: (CH)3CB (CH3)3C* + Br step 2 fast: (CH3)3C* + OH° → (CH)¿COH (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]"[B]"., where '1' is understood (so don't write it) for m, n etc.) Rate =
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Conversion of tert-Butyl Bromide to tert-Butyl Alcohol: Reaction Mechanism and Rate Law**
The following mechanism has been proposed for the conversion of tert-butyl bromide to tert-butyl alcohol in aqueous solution:
**Step 1 (slow):**
\[
\text{(CH}_3\text{)}_3\text{CBr} \rightarrow \text{(CH}_3\text{)}_3\text{C}^+ + \text{Br}^-
\]
**Step 2 (fast):**
\[
\text{(CH}_3\text{)}_3\text{C}^+ + \text{OH}^- \rightarrow \text{(CH}_3\text{)}_3\text{COH}
\]
**Questions:**
1. **What is the equation for the overall reaction?**
Use the smallest integer coefficients possible. If a box is not needed, leave it blank.
\[
\text{Reactants: }\_\_\_\_ + \_\_\_\_ \rightarrow \text{Products: }\_\_\_\_ + \_\_\_\_
\]
2. **Which species acts as a reaction intermediate?**
Enter formula. If none, leave box blank.
\[
\text{Intermediate: }\_\_\_\_
\]
3. **Complete the rate law for the overall reaction that is consistent with this mechanism.**
(Use the form \( k[\text{A}]^m[\text{B}]^n \), where '1' is understood (so don't write it) for \( m \), \( n \) etc.)
\[
\text{Rate} = \_\_\_\_
\]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc4eca0ea-f525-4d8f-9259-04e892974916%2Fe29da792-2112-4d7d-80a9-fcfb3239ac75%2F8b18lze_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Conversion of tert-Butyl Bromide to tert-Butyl Alcohol: Reaction Mechanism and Rate Law**
The following mechanism has been proposed for the conversion of tert-butyl bromide to tert-butyl alcohol in aqueous solution:
**Step 1 (slow):**
\[
\text{(CH}_3\text{)}_3\text{CBr} \rightarrow \text{(CH}_3\text{)}_3\text{C}^+ + \text{Br}^-
\]
**Step 2 (fast):**
\[
\text{(CH}_3\text{)}_3\text{C}^+ + \text{OH}^- \rightarrow \text{(CH}_3\text{)}_3\text{COH}
\]
**Questions:**
1. **What is the equation for the overall reaction?**
Use the smallest integer coefficients possible. If a box is not needed, leave it blank.
\[
\text{Reactants: }\_\_\_\_ + \_\_\_\_ \rightarrow \text{Products: }\_\_\_\_ + \_\_\_\_
\]
2. **Which species acts as a reaction intermediate?**
Enter formula. If none, leave box blank.
\[
\text{Intermediate: }\_\_\_\_
\]
3. **Complete the rate law for the overall reaction that is consistent with this mechanism.**
(Use the form \( k[\text{A}]^m[\text{B}]^n \), where '1' is understood (so don't write it) for \( m \), \( n \) etc.)
\[
\text{Rate} = \_\_\_\_
\]
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