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The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH,Cl2 ACN CO,Et AcO,EL CO,Et + NC -78°C, 8h CN 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1st order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.

The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH,Cl2 ACN CO,Et AcO,EL CO,Et + NC -78°C, 8h CN 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1st order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH2CI2 -CO,Et + ACN ACO,E NC -78°C, 8h CO,Et 1 ČN 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1st order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.
Transcribed Image Text:The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH2CI2 -CO,Et + ACN ACO,E NC -78°C, 8h CO,Et 1 ČN 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1st order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.
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