10. The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH,Cl, CO,Et + ACN Co,Et ACO,Et CN -78°C, 8h 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1s order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.
10. The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH,Cl, CO,Et + ACN Co,Et ACO,Et CN -78°C, 8h 25% 75% When cyclopentadiene is added in excess, the reaction is pseudo-1s order with respect to the fumaric nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol of ester.
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![10.
The following Diels-Alder cycloaddition was recently performed by Mukherjee et al.
CH,Cl,
CO,Et +
ACN
Co,Et
AcO,Et
CN
-78°C, 8h
25%
75%
When cyclopentadiene is added in excess, the reaction is pseudo-1“ order with respect to the fumaric
nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then
calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol
of ester.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F57a5127d-07a2-48e2-986e-67b601a3f8bd%2F8afeff33-85d0-454e-a35e-2fc4a36d5c6e%2F67wgb6o_processed.jpeg&w=3840&q=75)
Transcribed Image Text:10.
The following Diels-Alder cycloaddition was recently performed by Mukherjee et al.
CH,Cl,
CO,Et +
ACN
Co,Et
AcO,Et
CN
-78°C, 8h
25%
75%
When cyclopentadiene is added in excess, the reaction is pseudo-1“ order with respect to the fumaric
nitrile ester. If 4 hours represents the time for half of the original amount of ester to be consumed, then
calculate the amount of 1 and 2 diastereoisomers that are formed after 90 min if performed with 75.0 mmol
of ester.
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