The following character table (accompanied by a molecule of the corresponding point group) has some missing information. 2 C3 3 C2 2 S3 3 ov X1 1 1 1 1 1 1 x2+ y?, z2 1 1 -1 1 1 -1 Rz E' 2 -1 2 -1 (x, y) (x2- y?, xy) A;" 1 X2 1 -1 -1 -1 Az" 1 1 -1 -1 -1 1 X3 BH; E" -1 -2 1 (Rx, Ry) (2х, yz) а. Based on symmetry labels and Mulliken symbols, what is the missing symmetry element? b. Provide the missing information in the table: i. X1 = ii. X2 = iii. X3 = С. For this point group, what is the symmetry of the following orbitals for an atom located along the main C3 axis? i. A px orbital: ii. A d? orbital: iii. A dxy orbital:
The following character table (accompanied by a molecule of the corresponding point group) has some missing information. 2 C3 3 C2 2 S3 3 ov X1 1 1 1 1 1 1 x2+ y?, z2 1 1 -1 1 1 -1 Rz E' 2 -1 2 -1 (x, y) (x2- y?, xy) A;" 1 X2 1 -1 -1 -1 Az" 1 1 -1 -1 -1 1 X3 BH; E" -1 -2 1 (Rx, Ry) (2х, yz) а. Based on symmetry labels and Mulliken symbols, what is the missing symmetry element? b. Provide the missing information in the table: i. X1 = ii. X2 = iii. X3 = С. For this point group, what is the symmetry of the following orbitals for an atom located along the main C3 axis? i. A px orbital: ii. A d? orbital: iii. A dxy orbital:
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
Section: Chapter Questions
Problem 1E
Related questions
Question
![7.
The following character table (accompanied by a molecule of the corresponding point
group) has some missing information.
E
2 C3
3 C2
?
2 S3
3 oy
X1
1
1
1
1
1
x2+ y?, z2
A2
1
1
-1
1
-1
Rz
E'
2
-1
2
-1
(х, у)
(x2- у?, ху)
A,"
1
X2
1
-1
-1
-1
A2"
1
1
-1
-1
-1
1
X3
BH3
E"
2
-1
-2
1
(Rx, Ry)
(zx, yz)
а.
Based on symmetry labels and Mulliken symbols, what is the missing symmetry element?
b. Provide the missing information in the table:
i. X1 =
ii. X2 =
iii. X3 =
С.
For this point group, what is the symmetry of the following orbitals for an atom located along
the main C3 axis?
i. А Рх
orbital:
ii. A d,? orbital:
iii. A dxy orbital:](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1c04facf-07ed-4ba0-b632-2bed7ceb7fbe%2Fb70038b7-5f64-4542-9daa-10694e0161de%2Fc88jjnk_processed.jpeg&w=3840&q=75)
Transcribed Image Text:7.
The following character table (accompanied by a molecule of the corresponding point
group) has some missing information.
E
2 C3
3 C2
?
2 S3
3 oy
X1
1
1
1
1
1
x2+ y?, z2
A2
1
1
-1
1
-1
Rz
E'
2
-1
2
-1
(х, у)
(x2- у?, ху)
A,"
1
X2
1
-1
-1
-1
A2"
1
1
-1
-1
-1
1
X3
BH3
E"
2
-1
-2
1
(Rx, Ry)
(zx, yz)
а.
Based on symmetry labels and Mulliken symbols, what is the missing symmetry element?
b. Provide the missing information in the table:
i. X1 =
ii. X2 =
iii. X3 =
С.
For this point group, what is the symmetry of the following orbitals for an atom located along
the main C3 axis?
i. А Рх
orbital:
ii. A d,? orbital:
iii. A dxy orbital:
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