The following aromatic substitution reaction has been proposed to proceed via a radical chain reaction. H,N H,N + H,N The mechanism shown here has been proposed, where Ar is the aromatic ring. ArI + e ArtO (a) Identify each step as either initiation, propagation, or termination. (b) Sum the propagation steps to verify that the net equation matches that given in the problem ArtO → Ar• ARNH AINH Ar• + ArNH statement. ArI → ARNH2 + + ArI (c) Propose a possible termination step.
The following aromatic substitution reaction has been proposed to proceed via a radical chain reaction. H,N H,N + H,N The mechanism shown here has been proposed, where Ar is the aromatic ring. ArI + e ArtO (a) Identify each step as either initiation, propagation, or termination. (b) Sum the propagation steps to verify that the net equation matches that given in the problem ArtO → Ar• ARNH AINH Ar• + ArNH statement. ArI → ARNH2 + + ArI (c) Propose a possible termination step.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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