CH,CH,СH, CI CH,СНHCICH, + 2HCI 2CH,CH,СH, + 2C1, The chlorination of propane proceeds as a radical chain reaction. Sort the 7 reaction steps (you may need to scroll down to see them all) into categories of: Initiation Propagation Termination сн, сH,CH,. CH3CH2CH2 CH,CH, CH, -di: сHсHCH- di: а — б: — 2б Cl CH3CH2CH2 CнснсH. СH,сH,CH, -н CH3CHCH3 н— н—й: сн,бнсн, CH,CнсH, CH CHCH сH,снсH,

CH,CH,СH, CI CH,СНHCICH, + 2HCI 2CH,CH,СH, + 2C1, The chlorination of propane proceeds as a radical chain reaction. Sort the 7 reaction steps (you may need to scroll down to see them all) into categories of: Initiation Propagation Termination сн, сH,CH,. CH3CH2CH2 CH,CH, CH, -di: сHсHCH- di: а — б: — 2б Cl CH3CH2CH2 CнснсH. СH,сH,CH, -н CH3CHCH3 н— н—й: сн,бнсн, CH,CнсH, CH CHCH сH,снсH,

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Parts A - D.
nd no Consider the following mechanism. (1) CIO'(aq) + H2O(I) =HC10(aq) + OH (aq) [fast] (2) I "(aq) + HCIO(aq) →HIO(aq) + Cl "(aq) [slow] (3) OH (aq) + HIO(aq) →H2O(1) + IO*(aq) [fast] (a) What is the overall equation? (b) Identify the intermediates, if any. (c) What is the molecularity and the rate law for each step?
5c) Write the rate equation for the following SN1 reaction:
The following initial rate data are for the reaction of tertiary butyl bromide with hydroxide ion at 55 °C: (CH3)3CB + OH → (CH3)3COH + Br Experiment [(CH3)3CB1],, M [OH], M Initial Rate, Ms-1 1 0.890 1.50x10-3 1.50x10-3 3.01x10-3 3.01x10-3 0.118 0.118 2 1.78 0.890 1.78 3 0.237 4 0.237 Complete the rate law for this reaction in the box below. Use the form k[A]j™[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is
The activation energy for the gas phase decomposition of cyclobutane is 262 kJ. (CH₂) 4- →2 C₂H4 The rate constant at 721 K is 0.000401 /s. The rate constant will be 0.00338/s at K.
Alkoxides R-O can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH,CH,OH) used as solvent: Br + (1) Br(et) (et) + (et) CH,CH,OH + t-but-Br Ethoxide Isobutylene 10. What is the value of the rate constant for the synthesis of isobutylene at 25 °C? а) 6.8 х10-8 Trial Initial Initial Initial Rate (M/s) [t-but-Br] [Ethoxide] [isobutylene] b) 8.5 x10-7 6.8 x 10-8 13.6 х 10-8 1 0.08 M 0.04 M c) 2.1 x 10-5 0.16 M 0.04 M 0.08 M 0.08 M 6.8 x 10-8 13.6 x 10-8 d) 1.1 x10-5 3 0.08 M 4 0.16 M
Real Time uy 12. A particular reaction requires 54 kJ mol to activate and is found to have a rate constant 1 -1 -1 -1 S S of 3.42 x 10-4 M¹s¹ at 155.85 °C. Predict the rate constant (in M¹ s¹ to two decimal places) if the temperature was increased to 460.85 °C. Approximately how much faster (to the nearest whole number) is the reaction predicted at 460.85 °C relative to 155.85 °C? A: 540 times faster
What is the correct mechanism ?
6. Which of the following expressions is representative of the rate law for a Sy2 reaction ? 'N² k [electrophile] (b) Rate =k [electrophile] [nucleophile] (d) Rate = k[electrophile]? (a) Rate = (c) Rate =k [nucleophile]2
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