The enthalpy, H of a real gas is dependent on pressure, volume and temperature as described in equation 2.1: H = P(V-T (Hr)₂) dv (2.1) where P pressure (atm) T=temperature (K) V volume (L) Table 2.1 show the data taken for a real gas: Table 2.1 Data of a real gas V, L P, atm T = 350 K T = 400 K T = 450 K 650222248 0.1 220 250 282.5 4.1 4.7 5.23 10 2.2 2.5 2.7 1.35 1.49 1.55 1.1 1.2 1.24 30 0.90 0.99 1.03 0.68 0.75 0.78 0.61 0.675 0.7 0.54 0.6 0.62 a) Base on the data in Table 2.1, estimate the enthalpy of the real gas at the following pressure and temperature in Table 2.2 by using equation 2.1 and numerical differentiation to the order of O(h²).
The enthalpy, H of a real gas is dependent on pressure, volume and temperature as described in equation 2.1: H = P(V-T (Hr)₂) dv (2.1) where P pressure (atm) T=temperature (K) V volume (L) Table 2.1 show the data taken for a real gas: Table 2.1 Data of a real gas V, L P, atm T = 350 K T = 400 K T = 450 K 650222248 0.1 220 250 282.5 4.1 4.7 5.23 10 2.2 2.5 2.7 1.35 1.49 1.55 1.1 1.2 1.24 30 0.90 0.99 1.03 0.68 0.75 0.78 0.61 0.675 0.7 0.54 0.6 0.62 a) Base on the data in Table 2.1, estimate the enthalpy of the real gas at the following pressure and temperature in Table 2.2 by using equation 2.1 and numerical differentiation to the order of O(h²).
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
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
Transcribed Image Text:The enthalpy, H of a real gas is dependent on pressure, volume and temperature as described in
equation 2.1:
H = P(V-T (Hr)₂)
dv
(2.1)
where P pressure (atm)
T=temperature (K)
V volume (L)
Table 2.1 show the data taken for a real gas:
Table 2.1 Data of a real gas
V, L
P, atm
T = 350 K
T = 400 K
T = 450 K
650222248
0.1
220
250
282.5
4.1
4.7
5.23
10
2.2
2.5
2.7
1.35
1.49
1.55
1.1
1.2
1.24
30
0.90
0.99
1.03
0.68
0.75
0.78
0.61
0.675
0.7
0.54
0.6
0.62
a) Base on the data in Table 2.1, estimate the enthalpy of the real gas at the following pressure
and temperature in Table 2.2 by using equation 2.1 and numerical differentiation to the
order of O(h²).
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