For an ideal monatomic gas, the following is true. (Use the following as necessary: T, U, and V.) -UT

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Substitute the equation from Step 2 into the given equation for P and complete the partial derivative. (Use the following as necessary: kg, Q, T, U, and Up.)
P = -
-(3+),
T
- (ain(@)),
КВТ
=
KBT
Step 4 of 7
For an ideal monatomic gas, the following is true. (Use the following as necessary: T, U, and V.)
(3V)₁ = 1 UT
0
Step 5 of 7
Give the equation for the canonical partition function Q. Remember that only the translational partition function needs to be considered for an ideal monatomic gas. (Use the following as necessary: e, h, kg, m, N, T, T, and V.)
N
(2πmkBT) Ve
Nh³
Q =
(2µmkµT)h³v
X
Step 6 of 7
Determine In(Q) using the equation for Q from Step 5. (Use the following as necessary: e, h, kB, M, N, π, T, and V.)
Ve
In(Q)
N
In
(2μmkBT)
Nh³
(2π m kBT) e
N ln (V) + Nln
Nh³
Substitute into the equation for P from Step 3 and solve the partial derivative. (Use the following as necessary: e, h, kg, m, N, π, T, and V.)
NKB
T
P =
V
|KBTN-
V
Step 7 of 7
Rearrange the equation for P from Step 6 to solve for PV. (Use the following as necessary: KB, N, and T.)
PV =
KBTN
The number of particles, N, and the Boltzmann constant, kB, can be given in terms of Avogadro's constant, NA. (Use the following as necessary: n, NA, and R.)
PV
N =
КВТ
X
PV
KB
TN
X
Substitute these variables into the equation for PV and simplify. (Use the following as necessary: n, NA, R, and T.)
PV = nRT
Transcribed Image Text:Substitute the equation from Step 2 into the given equation for P and complete the partial derivative. (Use the following as necessary: kg, Q, T, U, and Up.) P = - -(3+), T - (ain(@)), КВТ = KBT Step 4 of 7 For an ideal monatomic gas, the following is true. (Use the following as necessary: T, U, and V.) (3V)₁ = 1 UT 0 Step 5 of 7 Give the equation for the canonical partition function Q. Remember that only the translational partition function needs to be considered for an ideal monatomic gas. (Use the following as necessary: e, h, kg, m, N, T, T, and V.) N (2πmkBT) Ve Nh³ Q = (2µmkµT)h³v X Step 6 of 7 Determine In(Q) using the equation for Q from Step 5. (Use the following as necessary: e, h, kB, M, N, π, T, and V.) Ve In(Q) N In (2μmkBT) Nh³ (2π m kBT) e N ln (V) + Nln Nh³ Substitute into the equation for P from Step 3 and solve the partial derivative. (Use the following as necessary: e, h, kg, m, N, π, T, and V.) NKB T P = V |KBTN- V Step 7 of 7 Rearrange the equation for P from Step 6 to solve for PV. (Use the following as necessary: KB, N, and T.) PV = KBTN The number of particles, N, and the Boltzmann constant, kB, can be given in terms of Avogadro's constant, NA. (Use the following as necessary: n, NA, and R.) PV N = КВТ X PV KB TN X Substitute these variables into the equation for PV and simplify. (Use the following as necessary: n, NA, R, and T.) PV = nRT
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