The Dieterici equation of state is similar to the van der Waals equation in that they both employ gas-specific constants a and b to attempt to account for the interaction between molecules and the nonzero volume of the individual molecules of gas. However, the Dieterici equation of state has a significantly different functional form: P(V – b) = RTe-a/(rVT) Note that a and b are constants (n is implicitly constant as volume is expressed as molar volume). What are the following partial derivatives for the Diererici equation of state? ӘР a) b) ƏP. T

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The Dieterici equation of state is similar to the van der Waals equation in that they
both employ gas-specific constants a and b to attempt to account for the interaction between
molecules and the nonzero volume of the individual molecules of gas. However, the Dieterici
equation of state has a significantly different functional form:
P(V – b) = RTe-a/(rVT)
Note that a and b are constants (n is implicitly constant as volume is expressed as molar
volume).
What are the following partial derivatives for the Diererici equation of state?
ӘР
a)
b)
ƏP.
T
Transcribed Image Text:The Dieterici equation of state is similar to the van der Waals equation in that they both employ gas-specific constants a and b to attempt to account for the interaction between molecules and the nonzero volume of the individual molecules of gas. However, the Dieterici equation of state has a significantly different functional form: P(V – b) = RTe-a/(rVT) Note that a and b are constants (n is implicitly constant as volume is expressed as molar volume). What are the following partial derivatives for the Diererici equation of state? ӘР a) b) ƏP. T
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