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The decomposition of nitramide, O,NNH,, in water has the chemical equation and rate law ► N,O(g) + H,O(1) [0,NNH,] [H*] O,NNH,(aq) – rate = k A proposed mechanism for this reaction is k1 1. O,NNH,(aq) 0,NNH (aq) + H*(aq) (fast equilibrium) k-1 k2 2. 0,NNH (aq) N2O(g) + OH (aq) (slow) 3. H' (aq) + OН (аq) H,O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism?

The decomposition of nitramide, O,NNH,, in water has the chemical equation and rate law ► N,O(g) + H,O(1) [0,NNH,] [H*] O,NNH,(aq) – rate = k A proposed mechanism for this reaction is k1 1. O,NNH,(aq) 0,NNH (aq) + H*(aq) (fast equilibrium) k-1 k2 2. 0,NNH (aq) N2O(g) + OH (aq) (slow) 3. H' (aq) + OН (аq) H,O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The decomposition of nitramide, 0,NNH,, in water has the chemical equation and rate law [0,NNH,] [H*] rate = k 0,NNH, (aq) → N,0(g) + H,O(1) A proposed mechanism for this reaction is k1 1. 0,NNH,(aq) O,NNH¯(aq) + H*(aq) (fast equilibrium) k-1 k2 2. Ο,ΝΝΗ (aq) N,0(g) + OH¯(aq) (slow) k3 3. H*(aq) + OH¯(aq) → H,O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? Answer Bank k = k1 k3 k2 k-1
Transcribed Image Text:The decomposition of nitramide, 0,NNH,, in water has the chemical equation and rate law [0,NNH,] [H*] rate = k 0,NNH, (aq) → N,0(g) + H,O(1) A proposed mechanism for this reaction is k1 1. 0,NNH,(aq) O,NNH¯(aq) + H*(aq) (fast equilibrium) k-1 k2 2. Ο,ΝΝΗ (aq) N,0(g) + OH¯(aq) (slow) k3 3. H*(aq) + OH¯(aq) → H,O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? Answer Bank k = k1 k3 k2 k-1
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in above given equation reaction 2nd is slowest stop of the reaction so, we assume that it is  the rate determination step of the reaction;

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