The decomposition of calcium carbonate is described by this reaction: CACO:(s) = CaO(s) + CO:(g) The partial pressure of CO:(g) has been measured over a wide temperature range and has been plotted below (une)

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The decomposition of calcium carbonate is described by this reaction:
CACO:(s) = CaO(s) + CO:(g)
The partial pressure of CO:(g) has been measured over a wide temperature range and has been
plotted below
E 10-
slope = -20500
intercept = +17.6
0.0010 0.0012 0.0014
1/T (K)
(a) Write down an expression for the equilibrium constant K, for the reaction above:
(b) Calculate values of AH° and AS° for the reaction.
(c) Explain the sign of AS® that you have determined?
(d) Explain what it would mean if the above plot was not linear?
In p (atm)
Transcribed Image Text:The decomposition of calcium carbonate is described by this reaction: CACO:(s) = CaO(s) + CO:(g) The partial pressure of CO:(g) has been measured over a wide temperature range and has been plotted below E 10- slope = -20500 intercept = +17.6 0.0010 0.0012 0.0014 1/T (K) (a) Write down an expression for the equilibrium constant K, for the reaction above: (b) Calculate values of AH° and AS° for the reaction. (c) Explain the sign of AS® that you have determined? (d) Explain what it would mean if the above plot was not linear? In p (atm)
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