The decomposition of calcium carbonate is described by this reaction:CACO:(s) = CaO(s) + CO:(g)The partial pressure of CO:(g) has been measured over a wide temperature range and has beenplotted belowE 10-slope = -20500intercept = +17.60.0010 0.0012 0.00141/T (K)(a) Write down an expression for the equilibrium constant K, for the reaction above:(b) Calculate values of AH° and AS° for the reaction.(c) Explain the sign of AS® that you have determined?(d) Explain what it would mean if the above plot was not linear?In p (atm)

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The decomposition of calcium carbonate is described by this reaction: CACO:(s) = CaO(s) + CO:(g) The partial pressure of CO:(g) has been measured over a wide temperature range and has been plotted below (une)

The decomposition of calcium carbonate is described by this reaction: CACO:(s) = CaO(s) + CO:(g) The partial pressure of CO:(g) has been measured over a wide temperature range and has been plotted below (une)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Thermochemistry

Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.

Exergonic Reaction

The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.

Question

The decomposition of calcium carbonate is described by this reaction:
CACO:(s) = CaO(s) + CO:(g)
The partial pressure of CO:(g) has been measured over a wide temperature range and has been
plotted below
E 10-
slope = -20500
intercept = +17.6
0.0010 0.0012 0.0014
1/T (K)
(a) Write down an expression for the equilibrium constant K, for the reaction above:
(b) Calculate values of AH° and AS° for the reaction.
(c) Explain the sign of AS® that you have determined?
(d) Explain what it would mean if the above plot was not linear?
In p (atm)

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