The compound [14]-annulene shows only two 'H NMR signals - one at ~0 ppm and the other ~7.6 ppm. Using benzene as a model for diamagnetic anisotropy, which of the following is expected to be true for the H signals of {14}-annulene as shown to the right? [Note: coding here is Red = outer H's, Blue = inner H's] H. H. HH H. a. The blue are 7.6 ppm and the blue are 0 ppm b. The red are 7.6 ppm and the red are 0 ppm c. Some of the red and some of the blue give rise to each signal d. The inner protons of all annulenes form an H-bonding complex called the diagmagnetic quatro-orbitrap that always shows a signal at -8 ppm. e. More information is needed
The compound [14]-annulene shows only two 'H NMR signals - one at ~0 ppm and the other ~7.6 ppm. Using benzene as a model for diamagnetic anisotropy, which of the following is expected to be true for the H signals of {14}-annulene as shown to the right? [Note: coding here is Red = outer H's, Blue = inner H's] H. H. HH H. a. The blue are 7.6 ppm and the blue are 0 ppm b. The red are 7.6 ppm and the red are 0 ppm c. Some of the red and some of the blue give rise to each signal d. The inner protons of all annulenes form an H-bonding complex called the diagmagnetic quatro-orbitrap that always shows a signal at -8 ppm. e. More information is needed
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The compound [14]-annulene shows only two 'H NMR signals - one at ~0 ppm and the other ~7.6 ppm. Using benzene as a
model for diamagnetic anisotropy, which of the following is expected to be true for the 'H signals of {14}-annulene as shown
to the right? [Note: coding here is Red = outer H's, Blue = inner H's]
H H'
H H
a. The blue are 7.6 ppm and the blue are 0 ppm
b. The red are 7.6 ppm and the red are 0 ppm
c. Some of the red and some of the blue give rise to each signal
d. The inner protons of all annulenes form an H-bonding complex called the diagmagnetic quatro-orbitrap that always shows a
signal at ~8 ppm.
e. More information is needed](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0c5bfc5d-3b7f-4351-8bf4-a98928c68bf4%2Ffe076a1e-5337-44dd-8f0f-529f5cb42196%2Fv1gqhyi_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The compound [14]-annulene shows only two 'H NMR signals - one at ~0 ppm and the other ~7.6 ppm. Using benzene as a
model for diamagnetic anisotropy, which of the following is expected to be true for the 'H signals of {14}-annulene as shown
to the right? [Note: coding here is Red = outer H's, Blue = inner H's]
H H'
H H
a. The blue are 7.6 ppm and the blue are 0 ppm
b. The red are 7.6 ppm and the red are 0 ppm
c. Some of the red and some of the blue give rise to each signal
d. The inner protons of all annulenes form an H-bonding complex called the diagmagnetic quatro-orbitrap that always shows a
signal at ~8 ppm.
e. More information is needed
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