The Clausius-Clapeyron Equation (hopefully introduced to you in General Chemistry) can be used to relate the temperature and vapor pressure of a pure liquid given its heat of vaporization. It can be used to create a specialized nomograph for each compound as shown in Figure 6.1 of your text for hydrocarbons and carboxylic acids. In a simplified form it is given in Equation 6.1 of your book for nitrobenzene. AHap In ( )= (-) Given that: .0°C 273.15 "K, Hvap(benzaldehyde) = 45.9 kj/mol benzaldehyde boils at 180 °C at 1 atm (760 mm Hg or torr), and that the ideal gas constant is 8.314 4621 J/K mol; at what temperature in °C should benzaldehyde distill if your vacuum pressure is 82 mm Hg? Provide 2 significant digits in your answers, for instance, 559 should be rounded to 560.

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The Clausius-Clapeyron Equation (hopefully introduced to you in General Chemistry) can be used to relate the temperature and vapor pressure of a pure liquid given its heat of vaporization. It can be used to create a specialized nomograph for each compound as
shown in Figure 6.1 of your text for hydrocarbons and carboxylic acids. In a simplified form it is given in Equation 6.1 of your book for nitrobenzene.
In (P) G/₂2 1)
AHvap
R
Given that:
• 0 °C 273.15 °K,
• Hvap(benzaldehyde) = 45.9 kj/mol,
• benzaldehyde boils at 180 °C at 1 atm (760 mm Hg or torr),
• and that the ideal gas constant is 8.314 4621 j/ºK mol;
at what temperature in °C should benzaldehyde distill if your vacuum pressure is 82 mm Hg?
Provide 2 significant digits in your answers, for instance, 559 should be rounded to 560.
Transcribed Image Text:Question 4 The Clausius-Clapeyron Equation (hopefully introduced to you in General Chemistry) can be used to relate the temperature and vapor pressure of a pure liquid given its heat of vaporization. It can be used to create a specialized nomograph for each compound as shown in Figure 6.1 of your text for hydrocarbons and carboxylic acids. In a simplified form it is given in Equation 6.1 of your book for nitrobenzene. In (P) G/₂2 1) AHvap R Given that: • 0 °C 273.15 °K, • Hvap(benzaldehyde) = 45.9 kj/mol, • benzaldehyde boils at 180 °C at 1 atm (760 mm Hg or torr), • and that the ideal gas constant is 8.314 4621 j/ºK mol; at what temperature in °C should benzaldehyde distill if your vacuum pressure is 82 mm Hg? Provide 2 significant digits in your answers, for instance, 559 should be rounded to 560.
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