The calibration of a calorimeter is done by using 13.00mL of 0.104M NaOH and 11.29mL of 0.125M HCl (deltaH=-55.85 kJ/mol). An increase in temperature, 4.6 degC is recorded. In the similar calorimeter, 7.58mL of 0.151M of a compound X(OH)3 reacts with 9.60mL of 0.125M HCl. The temperature changed from 25.9degC to 23.4degC. Determine the heat capacity of calorimeter, ad the enthalpy of the reaction of X(OH)3 and HCl.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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