The bromination of acetone is shown below.... CH3COCH3 Experiment 1 2 The rate of the reaction was measured for several different concentrations of acetone, bromine, and Ht at a certain temperature. Im + 5 Br2 + H+ Concentration CH3COCH 3 (M) 0.30 0.30 0.30 0.40 CH3COCH₂Br + HBr 0.40 Concentration Br2 (M) 0.050 0.10 0.050 0.050 0.050 Concentration H+ (M) 0.050 0.050 0.10 0.20 0.050 Rate of Reaction (m/s) 5.7 x 10-5 5.7 x 10-5 1.2 x 10-4 3.1 x 10-4 7.6 x 10-5 a. What is the rate law expression for this reaction. Be sure to indicate how you arrived at your answer. Show your work and answer to this question on t scratch paper clearly labeled. b. What is the value of k? What are the units for k? Show your work and answer on the scratch piece of paper clearly labeled. c. What will happen to the rate if the concentration of H+ is tripled? Answer this question on the scratch paper clearly labeled. d. What will happen to the rate if the concentration of CH3COCH3 is tripled, the Br2 concentration is doubled and the H* concentration is unchanged? A this question on the scratch paper clearly labeled.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**The Bromination of Acetone**

**Chemical Reaction:**
\[
\text{CH}_3\text{COCH}_3 + \text{Br}_2 + \text{H}^+ \rightarrow \text{CH}_3\text{COCH}_2\text{Br} + \text{HBr}
\]

The rate of the reaction was measured for several different concentrations of acetone, bromine, and \(\text{H}^+\) at a certain temperature.

**Table of Experimental Data:**

| Experiment | Concentration \(\text{CH}_3\text{COCH}_3\) (M) | Concentration \(\text{Br}_2\) (M) | Concentration \(\text{H}^+\) (M) | Rate of Reaction (M/s)   |
|------------|-----------------------------------------------|----------------------------------|---------------------------------|---------------------------|
| 1          | 0.30                                          | 0.050                            | 0.050                           | \(5.7 \times 10^{-5}\)    |
| 2          | 0.30                                          | 0.10                             | 0.050                           | \(5.7 \times 10^{-5}\)    |
| 3          | 0.30                                          | 0.050                            | 0.10                            | \(1.2 \times 10^{-4}\)    |
| 4          | 0.40                                          | 0.050                            | 0.20                            | \(3.1 \times 10^{-4}\)    |
| 5          | 0.40                                          | 0.050                            | 0.050                           | \(7.6 \times 10^{-5}\)    |

**Questions for Analysis:**

a. **What is the rate law expression for this reaction?**  
   - Be sure to indicate how you arrived at your answer.

b. **What is the value of \(k\)? What are the units for \(k\)?**  
   - Show your work and answer on the scratch paper clearly labeled.

c. **What will happen to the rate if the concentration of \(\text{H}^+\) is tripled?**  
   - Answer this question on the scratch paper clearly labeled.

d. **What will happen to the rate if the concentration of
Transcribed Image Text:**The Bromination of Acetone** **Chemical Reaction:** \[ \text{CH}_3\text{COCH}_3 + \text{Br}_2 + \text{H}^+ \rightarrow \text{CH}_3\text{COCH}_2\text{Br} + \text{HBr} \] The rate of the reaction was measured for several different concentrations of acetone, bromine, and \(\text{H}^+\) at a certain temperature. **Table of Experimental Data:** | Experiment | Concentration \(\text{CH}_3\text{COCH}_3\) (M) | Concentration \(\text{Br}_2\) (M) | Concentration \(\text{H}^+\) (M) | Rate of Reaction (M/s) | |------------|-----------------------------------------------|----------------------------------|---------------------------------|---------------------------| | 1 | 0.30 | 0.050 | 0.050 | \(5.7 \times 10^{-5}\) | | 2 | 0.30 | 0.10 | 0.050 | \(5.7 \times 10^{-5}\) | | 3 | 0.30 | 0.050 | 0.10 | \(1.2 \times 10^{-4}\) | | 4 | 0.40 | 0.050 | 0.20 | \(3.1 \times 10^{-4}\) | | 5 | 0.40 | 0.050 | 0.050 | \(7.6 \times 10^{-5}\) | **Questions for Analysis:** a. **What is the rate law expression for this reaction?** - Be sure to indicate how you arrived at your answer. b. **What is the value of \(k\)? What are the units for \(k\)?** - Show your work and answer on the scratch paper clearly labeled. c. **What will happen to the rate if the concentration of \(\text{H}^+\) is tripled?** - Answer this question on the scratch paper clearly labeled. d. **What will happen to the rate if the concentration of
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