The article "Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to Mixed Aqueous Organic Solvents" (G. Hefter, Y. Marcus, and W. Waghome, Chemical Reviews, 2002-2773-2836) presents measurements of entropy and enthalpy changes for many salts under a variety of conditions. The following table presents the results for enthalpy of transfer (in kJ/mol) from water to water + methanol of NaCi (table salt) for several concentrations of methanol. Four independent measurements were made at each concentration. Concentration (%) Enthalpy 1.62 1.60 1.62 1.66 10 3.56 3.35 2.69 2.66 2.72 2.73 20 3.45 3.65 3.52 30 3.18 3.40 3.06 a Is it plausible that the enthalpy is the same at all concentrations? Explain. b. Which pairs of concentrations, if any, can you conclude to have differing enthalpies?
The article "Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to Mixed Aqueous Organic Solvents" (G. Hefter, Y. Marcus, and W. Waghome, Chemical Reviews, 2002-2773-2836) presents measurements of entropy and enthalpy changes for many salts under a variety of conditions. The following table presents the results for enthalpy of transfer (in kJ/mol) from water to water + methanol of NaCi (table salt) for several concentrations of methanol. Four independent measurements were made at each concentration. Concentration (%) Enthalpy 1.62 1.60 1.62 1.66 10 3.56 3.35 2.69 2.66 2.72 2.73 20 3.45 3.65 3.52 30 3.18 3.40 3.06 a Is it plausible that the enthalpy is the same at all concentrations? Explain. b. Which pairs of concentrations, if any, can you conclude to have differing enthalpies?
MATLAB: An Introduction with Applications
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ISBN:9781119256830
Author:Amos Gilat
Publisher:Amos Gilat
Chapter1: Starting With Matlab
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Transcribed Image Text:The article "Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to
Mixed Aqueous Organic Solvents" (G. Hefter, Y. Marcus, and W. Waghome, Chemical
Reviews, 2002-2773-2836) presents measurements of entropy and enthalpy
changes for many salts under a variety of conditions. The following table presents
the results for enthalpy of transfer (in kJ/mol) from water to water + methanol of NaCi
(table salt) for several concentrations of methanol. Four independent measurements were
made at each concentration.
Concentration (%)
Enthalpy
1.62
1.60
1.62
1.66
10
3.56
3.35
2.69
2.66
2.72
2.73
20
3.45
3.65
3.52
30
3.18
3.40
3.06
a Is it plausible that the enthalpy is the same at all concentrations? Explain.
b. Which pairs of concentrations, if any, can you conclude to have differing enthalpies?
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