The article "Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to Mixed Aqueous Organic Solvents" (G. Hefter, Y. Marcus, and W. Waghorne, Chemical Reviews, 2002:2773–2836) presents measurements of entropy and enthalpy changes for many salts under a variety of conditions. The following table presents the results for entropies of transfer (in J/K · mol) from water to water + methanol of NaCl (table salt) over a range of concentrations of methanol: Concentration (%) Entropy 5 10 -1 20 -7 30 -17 40 -28 50 -39 60 -52 70 -65 80 -80 90 -98 100 -121 Fit polynomial models of degrees 1, 2, and 3 to predict the entropy (y) from the concentration (x). a. b. Which degree polynomial is the most appropriate? Explain. Using the most appropriate model, find 99% confidence intervals for the coefficients. C.
The article "Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to Mixed Aqueous Organic Solvents" (G. Hefter, Y. Marcus, and W. Waghorne, Chemical Reviews, 2002:2773–2836) presents measurements of entropy and enthalpy changes for many salts under a variety of conditions. The following table presents the results for entropies of transfer (in J/K · mol) from water to water + methanol of NaCl (table salt) over a range of concentrations of methanol: Concentration (%) Entropy 5 10 -1 20 -7 30 -17 40 -28 50 -39 60 -52 70 -65 80 -80 90 -98 100 -121 Fit polynomial models of degrees 1, 2, and 3 to predict the entropy (y) from the concentration (x). a. b. Which degree polynomial is the most appropriate? Explain. Using the most appropriate model, find 99% confidence intervals for the coefficients. C.
MATLAB: An Introduction with Applications
6th Edition
ISBN:9781119256830
Author:Amos Gilat
Publisher:Amos Gilat
Chapter1: Starting With Matlab
Section: Chapter Questions
Problem 1P
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