The 100. mL of buffer solution is 0.05 M in C2H3O2- and 0.10 M in HC2H3O2. What is the resulting pH when 20.0 mL of 0.1 M HCl is added to the buffer? Ka of HC2H3O2 = 1.8×10-5 pH after strong acid added = [?] pH of Soln w/ Acid Enter

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
### Buffer Solution pH Calculation

**Problem Statement:**
100 mL of buffer solution contains 0.05 M in C₂H₃O₂⁻ and 0.10 M in HC₂H₃O₂. What is the resulting pH when 20.0 mL of 0.1 M HCl is added to the buffer?

1. **Given Data:**
   - Buffer Solution Volume: 100 mL
   - Concentration of C₂H₃O₂⁻: 0.05 M
   - Concentration of HC₂H₃O₂: 0.10 M
   - Added HCl Volume: 20.0 mL
   - Concentration of HCl: 0.1 M
   - Acid Dissociation Constant (Kₐ) for HC₂H₃O₂: \( 1.8 \times 10^{-5} \)

2. **Calculation Goal:**
   Determine the resulting pH after the addition of the strong acid (HCl) to the buffer solution.

### Steps to Calculate pH After Adding Strong Acid:

1. **Calculate the Initial Moles:**
   - Moles of C₂H₃O₂⁻: \( 0.05 \times 0.1 \) = 0.005 moles
   - Moles of HC₂H₃O₂: \( 0.10 \times 0.1 \) = 0.010 moles

2. **Calculate the Moles of HCl Added:**
   - Moles of HCl: \( 0.1 \times 0.02 \) = 0.002 moles

3. **Reaction of HCl with C₂H₃O₂⁻:**
   HCl will react with C₂H₃O₂⁻ to form HC₂H₃O₂.
   \[ C₂H₃O₂⁻ + HCl \rightarrow HC₂H₃O₂ \]

   - Moles of C₂H₃O₂⁻ Left: 0.005 - 0.002 = 0.003 moles
   - Moles of HC₂H₃O₂ Formed: 0.010 + 0.002 = 0.012 moles

4. **Calculate the New Concentr
Transcribed Image Text:### Buffer Solution pH Calculation **Problem Statement:** 100 mL of buffer solution contains 0.05 M in C₂H₃O₂⁻ and 0.10 M in HC₂H₃O₂. What is the resulting pH when 20.0 mL of 0.1 M HCl is added to the buffer? 1. **Given Data:** - Buffer Solution Volume: 100 mL - Concentration of C₂H₃O₂⁻: 0.05 M - Concentration of HC₂H₃O₂: 0.10 M - Added HCl Volume: 20.0 mL - Concentration of HCl: 0.1 M - Acid Dissociation Constant (Kₐ) for HC₂H₃O₂: \( 1.8 \times 10^{-5} \) 2. **Calculation Goal:** Determine the resulting pH after the addition of the strong acid (HCl) to the buffer solution. ### Steps to Calculate pH After Adding Strong Acid: 1. **Calculate the Initial Moles:** - Moles of C₂H₃O₂⁻: \( 0.05 \times 0.1 \) = 0.005 moles - Moles of HC₂H₃O₂: \( 0.10 \times 0.1 \) = 0.010 moles 2. **Calculate the Moles of HCl Added:** - Moles of HCl: \( 0.1 \times 0.02 \) = 0.002 moles 3. **Reaction of HCl with C₂H₃O₂⁻:** HCl will react with C₂H₃O₂⁻ to form HC₂H₃O₂. \[ C₂H₃O₂⁻ + HCl \rightarrow HC₂H₃O₂ \] - Moles of C₂H₃O₂⁻ Left: 0.005 - 0.002 = 0.003 moles - Moles of HC₂H₃O₂ Formed: 0.010 + 0.002 = 0.012 moles 4. **Calculate the New Concentr
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Acid-Base Titrations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY