you want to separate Ni2+ and Mn2+ by precipitating the corresponding sulphides from each other. What pH value must you set so that one of the two metals is precipitated quantitatively (concentration in the solution less than/equal to 10/-5 mol/l) is precipitated while the other is still in solution?  Ksp (NiS): 10^-21, Kps (MnS): 10~15; Ks (H2S): 10 ~- 20, Saturation concentration of H2S in water: 0.1 mol/l

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 you want to separate Ni2+ and Mn2+ by precipitating the corresponding sulphides
from each other. What pH value must you set so that one of the two
metals is precipitated quantitatively (concentration in the solution less than/equal to 10/-5 mol/l)
is precipitated while the other is still in solution? 
Ksp (NiS): 10^-21, Kps (MnS): 10~15; Ks (H2S): 10 ~- 20,
Saturation concentration of H2S in water: 0.1 mol/l

 

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