/T (T) = -1×10-6 T2+ 7x10-5 T + 0.1253 nd integration of the function will represent the combined areas I and II from the plot shown below ne temperature range of analysis is 0.00 K→ 263.10 K. The heat of fusion is 1769 cal mol1 at the ormal melting point at 197.64 K and the heat of vaporization is 5960 cal mol1 at the normal boilin bint of 263.10 K. Note that no data is given for T < 15 K, therefore, we will not impose the Debye ube-Law in this problem. nd the molar entropy of gaseous SO2 in units of cal K1 mol1. Be mindful of the units being raluated here (i.e., calories). (Useful information: W. F. Giauque and C. C. Stephenson, J. Am. Chem. c. 1938, 60, 1389). You can access the previously mentioned article online via Zahnow library in If format. 0.16 0.14- 0.12- 0.1- 0.08- 0.06 Area I Area II 0.04- 0.02 C,I TI(cal K mol" )

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Cp/T (T) = -1×106 T2+ 7x10-5 T + 0.1253
and integration of the function will represent the combined areas I and II from the plot shown below.
The temperature range of analysis is 0.00 K → 263.10 K. The heat of fusion is 1769 cal mol-1 at the
normal melting point at 197.64 K and the heat of vaporization is 5960 cal mol-1 at the normal boiling
point of 263.10 K. Note that no data is given for T< 15 K, therefore, we will not impose the Debye
Cube-Law in this problem.
Find the molar entropy of gaseous SO2 in units of cal K1 mol1. Be mindful of the units being
evaluated here (i.e., calories). (Useful information: W. F. Giauque and C. C. Stephenson, J. Am. Chem.
Soc. 1938, 60, 1389). You can access the previously mentioned article online via Zahnow library in
pdf format.
0.16
0.14-
0.12-
0.1
0.08
0.06-
Area I
Area II
0.04-
0.02-
50
100
150
200
250
300
Temperature (K)
C,I TI( cal K? mol")
Transcribed Image Text:Cp/T (T) = -1×106 T2+ 7x10-5 T + 0.1253 and integration of the function will represent the combined areas I and II from the plot shown below. The temperature range of analysis is 0.00 K → 263.10 K. The heat of fusion is 1769 cal mol-1 at the normal melting point at 197.64 K and the heat of vaporization is 5960 cal mol-1 at the normal boiling point of 263.10 K. Note that no data is given for T< 15 K, therefore, we will not impose the Debye Cube-Law in this problem. Find the molar entropy of gaseous SO2 in units of cal K1 mol1. Be mindful of the units being evaluated here (i.e., calories). (Useful information: W. F. Giauque and C. C. Stephenson, J. Am. Chem. Soc. 1938, 60, 1389). You can access the previously mentioned article online via Zahnow library in pdf format. 0.16 0.14- 0.12- 0.1 0.08 0.06- Area I Area II 0.04- 0.02- 50 100 150 200 250 300 Temperature (K) C,I TI( cal K? mol")
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