Suppose 1.0 mole of oxalic acid, H2C204, is dissolved in 1.0L of water at 298K. a) Does dissociation of H2C2O4 or HC204 contribute more hydrogen ions to the system at equilibrium? Can we make the simplifying assumption that one source is dominant within the 5% test?

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Suppose 1.0 mole of oxalic acid, H2C204, is dissolved in 1.0L of water at 298K.
a) Does dissociation of H2C204 or HC204 contribute more hydrogen ions to the system at
equilibrium? Can we make the simplifying assumption that one source is dominant within
the 5% test?
b) What are the concentrations of H2C204, HC2O4', and C204² at equilibrium?
c) Under what conditions of Ka1 and Ka2 might the assumption made in (b) invalid?
Transcribed Image Text:Suppose 1.0 mole of oxalic acid, H2C204, is dissolved in 1.0L of water at 298K. a) Does dissociation of H2C204 or HC204 contribute more hydrogen ions to the system at equilibrium? Can we make the simplifying assumption that one source is dominant within the 5% test? b) What are the concentrations of H2C204, HC2O4', and C204² at equilibrium? c) Under what conditions of Ka1 and Ka2 might the assumption made in (b) invalid?
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