Sulfur dioxide and oxygen react to form sulfur trioxide, like this: 2 SO,(9)+O2(g) → 2 SO3(g) The reaction is exothermic. Suppose a mixture of SO,, O, and SO, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The temperature is lowered. to the left The pressure of SO3 will ? (none) to the right to the left The temperature is raised. The pressure of O2 will ? O (none)

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Sulfur dioxide and oxygen react to form sulfur trioxide, like this:
2 SO2(9)+O2(9) → 2 SO3(g)
The reaction is exothermic. Suppose a mixture of SO,, O, and SO, has come to equilibrium in a closed reaction vessel.
2'
Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel.
Also decide whether the equilibrium shifts to the right or left.
perturbation
change in composition
shift in equilibrium
to the right
The temperature is
lowered.
to the left
The pressure of SO3 will
?
(none)
to the right
to the left
The temperature is raised. The pressure of O2 will
?
(none)
O O O
Transcribed Image Text:Sulfur dioxide and oxygen react to form sulfur trioxide, like this: 2 SO2(9)+O2(9) → 2 SO3(g) The reaction is exothermic. Suppose a mixture of SO,, O, and SO, has come to equilibrium in a closed reaction vessel. 2' Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The temperature is lowered. to the left The pressure of SO3 will ? (none) to the right to the left The temperature is raised. The pressure of O2 will ? (none) O O O
- 1
-1
At a certain temperature the rate of this reaction is second order in CICH,CH,Cl with a rate constant of 9.84M
's':
CICH,CH,CI (g)
- CH,CHCI (g)+ HC1 (g)
Suppose a vessel contains CICH,CH,Cl at a concentration of 0.800M. Calculate the concentration of CICH,CH,Cl in the
vessel 0.850 seconds later. You may assume no other reaction is important.
Round your answer to 2 significant digits.
x10
Transcribed Image Text:- 1 -1 At a certain temperature the rate of this reaction is second order in CICH,CH,Cl with a rate constant of 9.84M 's': CICH,CH,CI (g) - CH,CHCI (g)+ HC1 (g) Suppose a vessel contains CICH,CH,Cl at a concentration of 0.800M. Calculate the concentration of CICH,CH,Cl in the vessel 0.850 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits. x10
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