Organomagnesium compounds
The interaction of alkyl halide with Mg metal in a suitable ether solvent is the common method for the synthesis of the Grignard reagent.
Hydrolysis Grignard Reactions and Reduction
Organomagnesium halides are Grignard reagents. Francois Auguste Victor Grignard, a French chemist who received the Nobel Prize in Chemistry in 1912, created these highly useful reagents.
Predict the structure (stereochemistry) of the dibromide products of a synaddition of bromine to trans-cinnamic acid. Predict the structure (stereochemistry) of the dibromide products of an antiaddition of bromine to trans-cinnamic acid.Label each product as threo or erytho.It may be helpful to construct molecular models of threo-and erytho-2,3-dibromo-3-phenylpropanioc acid.
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Br
Br
.CO2H
Br2
-CO2H
H
CH,Cl,
2,3-dibromo-3-phenylpropanoic acid
MW 308
trans-cinnamic acid
mp 133 °C
MW 148"
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