1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. CI OH majority isomere of A1 KOtBu ΑΙ + B DMSO H2SO4 equimolar mixture ΑΙ + A2
1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. CI OH majority isomere of A1 KOtBu ΑΙ + B DMSO H2SO4 equimolar mixture ΑΙ + A2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:1) In the following reactions, give the nature and possibly the stereochemistry of
A1, A2 and B and justify the proportions obtained.
4
1=3
|=1
CI
ull
OH
KOtBu
3
DMSO
H₂SO4
majority
A1
A1
+
2)When the first compound is treated with MeONa in methanol, compounds A1 and B are also
obtained, as well as a higher molecular weight compound C, which has a higher molecular weight. B
are also obtained as well as a higher molecular weight compound C whose 1H NMR spectrum is
given below. Justify the formation of C.
2
PPM
equimolar mixture
+
isomere of A1
1=3
mobilie
B
A2
1=3
1=3
1
1=3
O
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