Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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what is State the normalization condition for radial part of the atomic-orbital ?
this page will help in short answer please
![TABLE 6.4
The first few associated Laguerre polynomials.
n = 1,
n = 2,
n = 3,
n = 4,
1=0
1=0
1 = 1
1=0
1 = 1
1=2
1=0
1 = 1
1 = 2
1=3
L(x) = -1
L₂(x) = -2!(2-x)
L3(x) = -3!
L₁(x) = -3!(3 - 3x + 1x²)
L(x)=-4!(4x)
L(x) = -5!
L₁(x) = −4!(4 - 6x + 2x² − £x³)
L3(x) = -5!(10-5x + x²)
L(x) = -6!(6-x)
L'(x) = -7!
The functions given by Equation 6.47 may look complicated, but notice that each
one is just a polynomial multiplied by an exponential. The combinatorial factor in front
assures that the R₁ (r) are normalized with respect to an integration over r, or that the
R₁(r) satisfy
R² (r) R (r) r²dr = 1
Note that the volume element here is rdr, which is the "r" part of the spherical
coordinate volume element r² sin @drdodo.
The complete hydrogen atomic wave functions are
(6.48)
(6.49)
nim (r, 0, 0) = R₁ (r) Y™ (0, 0)
The first few hydrogen atomic wave functions are given in Table 6.5. The normalization
condition for hydrogen atomic wave functions is
[drr² de sino dom (r, 0, 0)nim (r, 0, 0) = 1
Because Ĥ is Hermitian (Section 4-5), the functions must also be orthogonal.
This orthogonality relationship is given by
(6.50)
f" drr² ["* de sine f
S™ dom (r, 0, 0)nim (r, 0, 0) = Enn Summ (6.51)
where the 8's are Krönecker deltas (Equation 4.30).
207](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6be53d9a-fc41-40fe-95cc-818e2301b0c8%2Faeffe892-4b64-4b2b-93e9-61339d7b2237%2Fmeb4hof_processed.jpeg&w=3840&q=75)
Transcribed Image Text:TABLE 6.4
The first few associated Laguerre polynomials.
n = 1,
n = 2,
n = 3,
n = 4,
1=0
1=0
1 = 1
1=0
1 = 1
1=2
1=0
1 = 1
1 = 2
1=3
L(x) = -1
L₂(x) = -2!(2-x)
L3(x) = -3!
L₁(x) = -3!(3 - 3x + 1x²)
L(x)=-4!(4x)
L(x) = -5!
L₁(x) = −4!(4 - 6x + 2x² − £x³)
L3(x) = -5!(10-5x + x²)
L(x) = -6!(6-x)
L'(x) = -7!
The functions given by Equation 6.47 may look complicated, but notice that each
one is just a polynomial multiplied by an exponential. The combinatorial factor in front
assures that the R₁ (r) are normalized with respect to an integration over r, or that the
R₁(r) satisfy
R² (r) R (r) r²dr = 1
Note that the volume element here is rdr, which is the "r" part of the spherical
coordinate volume element r² sin @drdodo.
The complete hydrogen atomic wave functions are
(6.48)
(6.49)
nim (r, 0, 0) = R₁ (r) Y™ (0, 0)
The first few hydrogen atomic wave functions are given in Table 6.5. The normalization
condition for hydrogen atomic wave functions is
[drr² de sino dom (r, 0, 0)nim (r, 0, 0) = 1
Because Ĥ is Hermitian (Section 4-5), the functions must also be orthogonal.
This orthogonality relationship is given by
(6.50)
f" drr² ["* de sine f
S™ dom (r, 0, 0)nim (r, 0, 0) = Enn Summ (6.51)
where the 8's are Krönecker deltas (Equation 4.30).
207
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