starting reactant IV target + enantiomer 1) BH3, THF 2) H₂O2, NaOH, H₂O 1) Hg(OAc)2, THF, H₂O (or ROH) 2) NaBH4 D2, Pt/C H₂, Pt/C D2, Lindlar catalyst or Ni₂B H₂, Lindlar catalyst or Ni₂B NaNH, OH/H₂O or SH/H₂S H₂O/H₂O 1) 03 2) H₂O 1) 03 2) (CH3)2S HBr, w/ROOR HBr, (cold, dark, no ROOR) Naº, NH3(e) NBS (trace Br2), light HgSO4, H2SO4, H₂O Naº, ROH 1) Sia₂BH, THF 2) H2O2, NaOH, H₂O H3O/ROH or H₂O*/RSH OR/ROH or SR/RSH 1) OsO4, NMO 2) NaHSO3, H₂O 1) MCPBA (peroxy acid) 2) H3O, H2O (or ROH or RSH) KMnO4 (warm, concentrated) Br₂/H₂O Br₂, heat or light Br2, cold, dark, no peroxides (CH3)3CO(CH3)3COH ROH or RSH H₂O KMnO4/OH (cold, dilute)
starting reactant IV target + enantiomer 1) BH3, THF 2) H₂O2, NaOH, H₂O 1) Hg(OAc)2, THF, H₂O (or ROH) 2) NaBH4 D2, Pt/C H₂, Pt/C D2, Lindlar catalyst or Ni₂B H₂, Lindlar catalyst or Ni₂B NaNH, OH/H₂O or SH/H₂S H₂O/H₂O 1) 03 2) H₂O 1) 03 2) (CH3)2S HBr, w/ROOR HBr, (cold, dark, no ROOR) Naº, NH3(e) NBS (trace Br2), light HgSO4, H2SO4, H₂O Naº, ROH 1) Sia₂BH, THF 2) H2O2, NaOH, H₂O H3O/ROH or H₂O*/RSH OR/ROH or SR/RSH 1) OsO4, NMO 2) NaHSO3, H₂O 1) MCPBA (peroxy acid) 2) H3O, H2O (or ROH or RSH) KMnO4 (warm, concentrated) Br₂/H₂O Br₂, heat or light Br2, cold, dark, no peroxides (CH3)3CO(CH3)3COH ROH or RSH H₂O KMnO4/OH (cold, dilute)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:starting reactant
IV
target
+ enantiomer
1) BH3, THF
2) H₂O2, NaOH, H₂O
1) Hg(OAc)2, THF, H₂O (or ROH)
2) NaBH4
D2, Pt/C
H₂, Pt/C
D2, Lindlar catalyst or Ni₂B
H₂, Lindlar catalyst or Ni₂B
NaNH,
OH/H₂O or SH/H₂S
H₂O/H₂O
1) 03
2) H₂O
1) 03
2) (CH3)2S
HBr, w/ROOR
HBr, (cold, dark, no ROOR)
Naº, NH3(e)
NBS (trace Br2), light
HgSO4, H2SO4, H₂O
Naº, ROH
1) Sia₂BH, THF
2) H2O2, NaOH, H₂O
H3O/ROH or H₂O*/RSH
OR/ROH or SR/RSH
1) OsO4, NMO
2) NaHSO3, H₂O
1) MCPBA (peroxy acid)
2) H3O, H2O (or ROH or RSH)
KMnO4 (warm, concentrated)
Br₂/H₂O
Br₂, heat or light
Br2, cold, dark, no peroxides
(CH3)3CO(CH3)3COH
ROH or RSH
H₂O
KMnO4/OH (cold, dilute)
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