Standard Addition Variable Volume Calibration Curve i. Use the following data and Excel to plot a standard addition variable volume calibration curve. Use your curve to determine the concentration (ppm) of the unknown sample. Save your calibration curve as a PDF file and upload to eClass. Use the following additional information to complete the table below. total volume (volume of standard + sample) volume of standard added . V ii. iii. Vs • Vo initial volume of sample= 50.0 mL S₁ initial concentration of standard = 279 ppm Is+x= signal measured for a sample containing unknown plus standard

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c) Standard Addition Variable Volume Calibration Curve
i.
ii.
iii.
Vs (ml)
0.0
0.05
0.25
0.40
0.55
0.70
0.85
1.0
1.15
Use the following data and Excel to plot a standard addition variable volume
calibration curve. Use your curve to determine the concentration (ppm) of the
unknown sample.
Save your calibration curve as a PDF file and upload to eClass.
Use the following additional information to complete the table below.
• V = total volume (volume of standard + sample)
• Vs = volume of standard added
• Vo initial volume of sample = 50.0 mL
• S₁ = initial concentration of standard = 279 ppm
• Is+x = signal measured for a sample containing unknown plus standard
V total (mL)
50.0
50.05
50.25
50.4
?
?
?
?
?
x-variable
Si *Vs/V. (ppm)
0.0
0.279
1.395
2.232
?
?
?
?
?
I(s+x) (μA)
1.84
1.95
2.81
3.5
3.88
4.39
4.86
5.45
5.67
y-variable
I(s+x) *V/V. (μA)
1.84
1.95195
2.82405
3.528
?
?
?
?
?
Transcribed Image Text:c) Standard Addition Variable Volume Calibration Curve i. ii. iii. Vs (ml) 0.0 0.05 0.25 0.40 0.55 0.70 0.85 1.0 1.15 Use the following data and Excel to plot a standard addition variable volume calibration curve. Use your curve to determine the concentration (ppm) of the unknown sample. Save your calibration curve as a PDF file and upload to eClass. Use the following additional information to complete the table below. • V = total volume (volume of standard + sample) • Vs = volume of standard added • Vo initial volume of sample = 50.0 mL • S₁ = initial concentration of standard = 279 ppm • Is+x = signal measured for a sample containing unknown plus standard V total (mL) 50.0 50.05 50.25 50.4 ? ? ? ? ? x-variable Si *Vs/V. (ppm) 0.0 0.279 1.395 2.232 ? ? ? ? ? I(s+x) (μA) 1.84 1.95 2.81 3.5 3.88 4.39 4.86 5.45 5.67 y-variable I(s+x) *V/V. (μA) 1.84 1.95195 2.82405 3.528 ? ? ? ? ?
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