SPh SPh Br H- H. c) d) :CH3 CH3 H-ö:

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer parts D,E,F

1) For the following transformations involving one elementary step each:
(i) Draw &+ and 8- on the atoms that are most electron deficient or electron rich on the starting material
which will help you to draw the mechanism (ii) provide mechanism arrows to describe electron flow for
these transformations (iii) name the elementary steps on blanks (not as important but useful for
recognition/categorization)
:Ci: O
:CEN
CN
a)
b)
:SPh
SPh
Br
H-O
c)
d)
H.
: CH3
CH3
H-0
e)
f)
Required format for multi-step mechanisms. Helps you keep track of
where you are heading and saves you having to redraw product!
:0:
:OCH3
O: OCH3
:0:
reagent(s)
reaction
conditions
Bonds Made Bonds Broken
SM
Product(s)
e.g. C1-02
C4-H
C3-04
CI:
OCH3
Intermediate
#1
so number your atoms on
SM to keep track of what
is
opening
reaction (=book keeping);
cross out bonds made/
broken as your
mechanism demonstrates
the
g)
Int. #4, etc.
Int. #2
Int. #3
each step)
Transcribed Image Text:1) For the following transformations involving one elementary step each: (i) Draw &+ and 8- on the atoms that are most electron deficient or electron rich on the starting material which will help you to draw the mechanism (ii) provide mechanism arrows to describe electron flow for these transformations (iii) name the elementary steps on blanks (not as important but useful for recognition/categorization) :Ci: O :CEN CN a) b) :SPh SPh Br H-O c) d) H. : CH3 CH3 H-0 e) f) Required format for multi-step mechanisms. Helps you keep track of where you are heading and saves you having to redraw product! :0: :OCH3 O: OCH3 :0: reagent(s) reaction conditions Bonds Made Bonds Broken SM Product(s) e.g. C1-02 C4-H C3-04 CI: OCH3 Intermediate #1 so number your atoms on SM to keep track of what is opening reaction (=book keeping); cross out bonds made/ broken as your mechanism demonstrates the g) Int. #4, etc. Int. #2 Int. #3 each step)
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