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SPh SPh Br H- H. c) d) :CH3 CH3 H-ö:

SPh SPh Br H- H. c) d) :CH3 CH3 H-ö:

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer parts D,E,F

1) For the following transformations involving one elementary step each: (i) Draw &+ and 8- on the atoms that are most electron deficient or electron rich on the starting material which will help you to draw the mechanism (ii) provide mechanism arrows to describe electron flow for these transformations (iii) name the elementary steps on blanks (not as important but useful for recognition/categorization) :Ci: O :CEN CN a) b) :SPh SPh Br H-O c) d) H. : CH3 CH3 H-0 e) f) Required format for multi-step mechanisms. Helps you keep track of where you are heading and saves you having to redraw product! :0: :OCH3 O: OCH3 :0: reagent(s) reaction conditions Bonds Made Bonds Broken SM Product(s) e.g. C1-02 C4-H C3-04 CI: OCH3 Intermediate #1 so number your atoms on SM to keep track of what is opening reaction (=book keeping); cross out bonds made/ broken as your mechanism demonstrates the g) Int. #4, etc. Int. #2 Int. #3 each step)
Transcribed Image Text:1) For the following transformations involving one elementary step each: (i) Draw &+ and 8- on the atoms that are most electron deficient or electron rich on the starting material which will help you to draw the mechanism (ii) provide mechanism arrows to describe electron flow for these transformations (iii) name the elementary steps on blanks (not as important but useful for recognition/categorization) :Ci: O :CEN CN a) b) :SPh SPh Br H-O c) d) H. : CH3 CH3 H-0 e) f) Required format for multi-step mechanisms. Helps you keep track of where you are heading and saves you having to redraw product! :0: :OCH3 O: OCH3 :0: reagent(s) reaction conditions Bonds Made Bonds Broken SM Product(s) e.g. C1-02 C4-H C3-04 CI: OCH3 Intermediate #1 so number your atoms on SM to keep track of what is opening reaction (=book keeping); cross out bonds made/ broken as your mechanism demonstrates the g) Int. #4, etc. Int. #2 Int. #3 each step)
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