Problem: A first order reaction is 75.0.1 complete in 320.s. a. what are the first and second half lives for this reaction b. How long does it take for 90.0%. Completion.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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## Formulas

- \( \ln [CA] = -kt + \ln [CA_0] \)

### Half-Life Formulas

- \( t_{1/2} = \frac{0.693}{k} \)
- \( k = \frac{0.693}{t_{1/2}} \)

### First Order Reaction

- \( \ln \frac{[CA_0]}{[CA]_t} = kt \)

### Concentration

- \( \% \left( [EA]_0 \right) = 100 \times \frac{[A]_t}{[A]_0} = \text{left} \)
- \( t = \frac{\ln \frac{[CA]_0}{[CA]_t}}{k'} \)

### Important Relationship

- \( \ln \frac{[OJO]_0}{[SJ]_t} = = kt \)
- \( k = \frac{\ln \frac{[CA]_0}{[CA]_t}}{t} \)

## Problem

A first order reaction is 75.0% complete in 320 s.

### Questions

a. What are the first and second half lives for this reaction?
b. How long does it take for 90.0% completion?
Transcribed Image Text:## Formulas - \( \ln [CA] = -kt + \ln [CA_0] \) ### Half-Life Formulas - \( t_{1/2} = \frac{0.693}{k} \) - \( k = \frac{0.693}{t_{1/2}} \) ### First Order Reaction - \( \ln \frac{[CA_0]}{[CA]_t} = kt \) ### Concentration - \( \% \left( [EA]_0 \right) = 100 \times \frac{[A]_t}{[A]_0} = \text{left} \) - \( t = \frac{\ln \frac{[CA]_0}{[CA]_t}}{k'} \) ### Important Relationship - \( \ln \frac{[OJO]_0}{[SJ]_t} = = kt \) - \( k = \frac{\ln \frac{[CA]_0}{[CA]_t}}{t} \) ## Problem A first order reaction is 75.0% complete in 320 s. ### Questions a. What are the first and second half lives for this reaction? b. How long does it take for 90.0% completion?
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