d) please see attached **Determining the Order of a Reaction with Respect to [M]***Problem Statement:*If a new reaction was run leaving [N] the same, but beginning (time = 0) with [M] = 0.204 M, A(545nm) = 0.981. After 30 seconds, A(545 nm) is 0.807. What is the order of the reaction with respect to [M]?*Explanation:*We are given initial conditions with specific absorbance values, measured at a wavelength of 545 nm. With these data points, the goal is to determine the reaction order with respect to the concentration of M, identified as [M]. - At time t = 0, the concentration of M is 0.204 M and the absorbance A(545nm) is 0.981.- After 30 seconds, the absorbance at 545 nm changes to 0.807. To determine the order of the reaction with respect to [M], we need to examine how the concentration of [M] affects the rate of the reaction. Using the change in absorbance over time at a specific wavelength, we can apply various rate laws and observe which one fits the data. **Steps to Determine the Order:**1. **Zero-Order Reaction:** - For a zero-order reaction, the rate of reaction is constant. - [M] would decrease linearly with time.2. **First-Order Reaction:** - The rate of reaction depends linearly on the concentration of [M]. - The plot of ln[M] versus time should be linear.3. **Second-Order Reaction:** - The rate is proportional to the square of the concentration of [M]. - The plot of 1/[M] versus time should be linear.Considering the given absorbance values, we can relate them to concentration changes using Beer's Law (A = εlc, where A is absorbance, ε is molar absorptivity, l is path length, and c is concentration). Since l and ε remain constant, any change in absorbance can be directly related to the change in concentration.Once you have these plots, identify the linear relationship among zero, first, or second-order reactions. The order in which the graphical representation (linear plot) fits best will indicate the order of reaction concerning [M].This step-by-step process is

The beer’s law explain that the concentration of a solution is directly proportional to the…

If a new reaction was run leaving [N] the same, but beginning (time = 0) with [M] = 0.204 M, A(545nm) = 0.981. After 30 seconds, A (545 nm) is 0.807. What is the order of the reaction with respect to [M] ?

If a new reaction was run leaving [N] the same, but beginning (time = 0) with [M] = 0.204 M, A(545nm) = 0.981. After 30 seconds, A (545 nm) is 0.807. What is the order of the reaction with respect to [M] ?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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