(a) Regarding the mental exercise of describing a particle in a box, answer the following with supporting diagrams and explanations. (i) Why is a particle in a 1-dimensional box used to allude to molecular orbital theory in chemistry? (ii) Describe the evolution of a particle in a 1-dimensional box, into a particle in a 3- dimensional box, and further to description of bonding in the context of molecular orbital theory. Justify your answer using well-labelled diagrams. (b) In a parallel universe, electrons and nuclei have identical masses, yet with all other aspects

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Chapter1: Chemical Foundations
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(a) Regarding the mental exercise of describing a particle in a box, answer the following with
supporting diagrams and explanations.
(i) Why is a particle in a 1-dimensional box used to allude to molecular orbital theory in
chemistry?
(ii) Describe the evolution of a particle in a 1-dimensional box, into a particle in a 3-
dimensional box, and further to description of bonding in the context of molecular
orbital theory. Justify your answer using well-labelled diagrams.
(b) In a parallel universe, electrons and nuclei have identical masses, yet with all other aspects
equivalent (energetics, equations, etc.). Predict the structure of benzene in this parallel
universe. Your answer should include detailed schematics and diagrams and/or equations to
support its conclusions.
Transcribed Image Text:(a) Regarding the mental exercise of describing a particle in a box, answer the following with supporting diagrams and explanations. (i) Why is a particle in a 1-dimensional box used to allude to molecular orbital theory in chemistry? (ii) Describe the evolution of a particle in a 1-dimensional box, into a particle in a 3- dimensional box, and further to description of bonding in the context of molecular orbital theory. Justify your answer using well-labelled diagrams. (b) In a parallel universe, electrons and nuclei have identical masses, yet with all other aspects equivalent (energetics, equations, etc.). Predict the structure of benzene in this parallel universe. Your answer should include detailed schematics and diagrams and/or equations to support its conclusions.
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