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Subject: Atomic and molecular physics
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- ch1(d) The Beer-Lambert law states that the absorbance (A) of light by a solution in a cuvette is given by: A = ln == ECL In == where lo is the incident light intensity, is the transmitted light intensity, e is the molar absorptivity, c is the concentration of the solution, and Lis the path length of the cuvette. (1) Light with a wavelength of 800 nm is passed through a cuvette containing a solution of Coumarin dye. After passing through the cuvette, the light intensity was reduced to 10% of its initial value. What is the absorbance of the solution of Coumarin dye? (1) The concentration of the Coumarin dye is 0.004 mol dm, and the cuvette has a path length of 1 cm. What is the molar absorptivity of Coumarin dye at 800 nm, in units of m² mor¹? (T) The molar absorptivity of Coumarin dye at 400 nm is three times larger than at 800 nm. How would the absorbance of the solution change, when measured with 400 nm light rather than 800 nm light?A molecular exclusion column has a diameter of 7.8 mm and a length of 30 cm. The solid portion of the particles occupies 20% of the volume, the pores occupy 40%, and the volume between particles occupies 40%. (a) At what volume would totally excluded molecules be expected to emerge? (b) At what volume would the smallest molecules be expected? (c) A mixture of polymers of various molecular masses is eluted between 23 and 27 mL. What does this imply about the retention mechanism for these solutes on the column?
- Atomic refractions: C(sp3): 2.8158; C(sp2): 3.8276; C(sp): 3.8974; H: 0.915. Knowing that the refractive index of benzene is 1.4956 (with the Na line D), indicate the molar volume of benzene.(1). 22.1 cm3/mol (2). 76.6 cm3/mol (3). 97.6 cm3/mol (4). 98.8 cm3/molAn ethanol solution of 3.5 mg/100 ml of compound Y (150.0 g/mol) in a 1.00 cm quartz cell has an extinction coefficient (ɛ) of 23,150 at Amax=235 nm. What is the expected absorption (A)? Report your answer to the correct number of significant figures.,A ALEKS - Julianna Graham - L x + ← → www-awu.aleks.com/alekscgi/x/Isl.exe/10_u-IgNslkr7j8P3JH-IQUHIQg6bJxmeSyVPHOEB1plef9xyC5Ca9QIUX9FDNS1kHQvOMzcrVprA IBP5q2HYWPCASZQKNla...✰ Ο Naming and Drawing Organic Molecules Numbering the main chain of branched alkanes For each organic compound in the table below, enter the locant of the highlighted side chain. compound locant of highlighted side chain CH₂ CH3-CH2-C- CH₂ T CH3 CH₁₂ | CH3-CH2-CH-CH-CH3 CH3 CH3 CH3-CH2-CH- CH3 Explanation Check esc F2 DOD D MacBook Air # 80 $ 000 F4 % & G F7 0/5 Julianna olo 2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accessibility FB F10 dele
- (d) The Beer-Lambert law states that the absorbance (A) of light by a solution in a cuvette is given by: 10 A = In == ECL where lo is the incident light intensity, is the transmitted light intensity, e is the molar absorptivity, c is the concentration of the solution, and L is the path length of the cuvette. (1) Light with a wavelength of 800 nm is passed through a cuvette containing a solution of Coumarin dye. After passing through the cuvette, the light intensity was reduced to 10% of its initial value. What is the absorbance of the solution of Coumarin dye? (ii) The concentration of the Coumarin dye is 0.004 mol dm3, and the cuvette has a path length of 1 cm. What is the molar absorptivity of Coumarin dye at 800 nm, in units of m² mot¹? (IT) The molar absorptivity of Coumarin dye at 400 nm is three times larger than at 800 nm. How would the absorbance of the solution change, when measured with 400 nm light rather than 800 nm light?ОН ОН PC13, (2equiv.,), DCMElectron config
- (d) The Beer-Lambert law states that the absorbance (A) of light by a solution in a cuvette is given by. A = ID==ecL In=-= where lo is the incident light intensity, / is the transmitted light intensity, e is the molar absorptivity, c is the concentration of the solution, and Lis the path length of the cuvette. (1) Light with a wavelength of 800 nm is passed through a cuvette containing a solution of Coumarin dye. After passing through the cuvette, the light intensity was reduced to 10% of its initial value. What is the absorbance of the solution of Coumarin dye? (1) The concentration of the Coumarin dye is 0.004 mol dm3, and the cuvette has a path length of 1 cm. What is the molar absorptivity of Coumarin dye at 800 nm, in units of m² mot¹?Be sure to answer all parts. Covalent bonds in a molecule abso rb radiation in the IR region and vibrate at characteristic frequencies. (a) A molecular vibration absorbs radiation of wavelength 176 µm. What frequency (in s) corresponds to that wavelength? Enter your answer in scientific notatio n. X 10 -1 (b) A molecular vibration has a frequency of vibration of 6.753 x 10 m) corresponds to that frequency? 13 Hz. What wavelength (in p IIO $4 %23 2 4 3. 7. e pCalculate the energy separations in joules, kilojoules per mole, and electronvolts, and as a wavenumber, between the levels (a) n = 3 and n = 1, (b) n = 7 and n = 6 of an electron in a one-dimensional nanoparticle modelled by a box of length 1.5 nm.
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