Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title: Molecular Orbital Theory: Understanding Magnetism in I₂**
**Task:**
Complete the MO diagram (below) to determine if I₂ is paramagnetic or diamagnetic.
**Molecular Orbital (MO) Diagram:**
The diagram consists of molecular orbitals represented by horizontal lines. Electrons are indicated by arrows filling these orbitals.
From bottom to top, the orbitals are labeled as follows:
1. **σs**: Lowest energy non-bonding orbital where electrons first populate.
2. **σs***: Anti-bonding orbital, indicated by an asterisk (*).
3. **σp**: Bonding orbital formed from the combination of p-orbitals.
4. **πp**: Two degenerate π (pi) orbitals that allow lateral overlap.
5. **πp\***: Two degenerate anti-bonding pi orbitals, indicated by an asterisk (*).
6. **σp\***: Highest energy orbital, also anti-bonding, indicated by an asterisk (*).
**Question:**
Is I₂:
A) Paramagnetic: Has unpaired electrons.
B) Diamagnetic: All electrons are paired.
**Instruction:**
Analyze the filled molecular orbitals for unpaired electrons to determine the magnetic property of I₂.
**Note:** For accurate results, fill the orbitals according to the electron configuration for I₂, considering the energy order and pauli exclusion principle.
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