sorbed molecule. Solve the probler e partition function of the system. nolecules.]
sorbed molecule. Solve the probler e partition function of the system. nolecules.]
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![4) A surface with No adsorption centers has N (S N,) gas molecules adsorbed on it. Show that the
chemical potential of the adsorbed molecules is given by u = kTIn-
N
(No-N)a(T)
where a(T) is the
partition function of a single adsorbed molecule. Solve the problem by constructing the grand
partition function as well as the partition function of the system. [Neglect the intermolecular
interaction among the adsorbed molecules.]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F86dcca9d-aebf-4587-96a4-20e7add623c2%2Ff35143d7-db37-42f9-ad29-a20056f3d1b2%2Fh3g60m_processed.jpeg&w=3840&q=75)
Transcribed Image Text:4) A surface with No adsorption centers has N (S N,) gas molecules adsorbed on it. Show that the
chemical potential of the adsorbed molecules is given by u = kTIn-
N
(No-N)a(T)
where a(T) is the
partition function of a single adsorbed molecule. Solve the problem by constructing the grand
partition function as well as the partition function of the system. [Neglect the intermolecular
interaction among the adsorbed molecules.]
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