SO2Cl2(g) is produced by this rxn: SO2(g) + Cl+(g) ⇄ SO2Cl2(g). A mixture of 1.00atm of SO2(g) and 1.00atm of Cl2(g) is placed in a rigid, evacuated 1.00L container, and the rxn mixture is allowed to reach equilibrium at a certain temperature.                          PSO2     PCl2      PSO2Cl2 Pinitial (atm)       1.00     1.00      0.00 Peq (atm)          0.20        ?        0.80 Which is the equilibrium value of PCl2 & value of the eq constant Kp?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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SO2Cl2(g) is produced by this rxn: SO2(g) + Cl+(g) ⇄ SO2Cl2(g).

A mixture of 1.00atm of SO2(g) and 1.00atm of Cl2(g) is placed in a rigid, evacuated 1.00L container, and the rxn mixture is allowed to reach equilibrium at a certain temperature. 

                        PSO2     PCl2      PSO2Cl2

Pinitial (atm)       1.00     1.00      0.00

Peq (atm)          0.20        ?        0.80

Which is the equilibrium value of PCl2 & value of the eq constant Kp?

a) PCl2 = 0.20 atm;  Kp = 20        b) PCl2 = 0.20 atm;  Kp = 0.050

c) PCl2 = 0.10 atm;  Kp = 5.0       d) PCl2 = 0.80 atm;  Kp = 0.025

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