Sketch the structure of the complex in each of the follow-ing compounds and give the full compound name:(a) cis-[Co(NH3)4(H,O),](NO;)2(b) Na,[Ru(H,O)Cl5](c) trans-NH4[Co(C;04)2(H2O)z](d) cis-[Ru(en);Cl2]

a) The Cis-[Co(NH3)4(H2O)2](NO3)2 complex is cis isomer that means the same ligands come on the same…

Answered: Sketch the structure of the complex in…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 95QRT

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Give the number of d electrons (n of dn) for the central metal ion in (a) [Cr(H2O)6](ClO3)2; (b) [Mn(CN)6]2-; (c) [Ru(NO)(en)2Cl]Br.
Sketch the following complexes. If more than one enantiomer exists, sketch just one.(a) mer-Cr(NH3)3(Cl)3 (b) cis-[Fe(H2O)4(CN)2]Cl (c) trans-[Ni(en)2Cl2] (d) fac-Co(NH3)3(CN)3
Assign a systematic name to each of the following chemical compounds:(a) NH4[Cr(NH3)2(NCS)4](b) [Tc(CO)5]I(c) K[Mn(CN)5](d) [Co(NH3)4(OH2)Cl]Br2
What type of isomerism is shown by the complex [Cr(H20)6]Cl3? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P. (iii) Write the hybridization and shape of [CoF6]3-. (Atomic number of Co = 27)
Determine the coordination number (c.n.) and the oxidation state (o.s.) of the transition metal in each of the following compounds or complex ions. (a) [Ti(H2O)6]3+ :(b) K4[Fe(CN)6] :(c) [Ni(H2O)2(en)2]SO4 : (d) Na[Cr(OH)4 :(e) [Co(en)2(NO2)]+ :
(i) What type of isomerism is shown by the complex [Cr(H2O)6]Cl3?(ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P.(iii) Write the hybridization and shape of [CoF6]3-.(Atomic number of Co = 27)
Determine the oxidation state of the coordinated metal atom in each of the following compounds:(a) K[Co(NH3)2(CN)4]; (b) Os(CO)5; (c) Na[Co(OH2)3(OH)3].
Give systematic names for the following formulas:(a) [Co(NH3)4(NO2)2]Cl (b) [Cr(NH3)6][Cr(CN)6] (c) K2[CuCl4]
Give systematic names for the following formulas:(a) [Co(NH3)4(NO2)2]Cl (b) [Cr(NH3)6][Cr(CN)6](c) K2[CuCl4]
Give the systematic name for each of the following chemical compounds:(a) [Ni(OH2)4(OH)2](b) [HgClI](c) K4[Os(CN)6](d) [FeBrCl(en)2]Cl
What type of isomerism is shown by [CO(NH3)5ONO]Cl2? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if A0 < P. (iii) Write the hybridization and shape of [Fe(CN)6]3-. (Atomic number of Fe — 26)
If a solution known to be made up of an octahedral cobalt complex ion [Co(NH3)6]3+ appears orange to the eye, (a) What wavelength of light does it absorb from the color wheel? Please explain. (b) What is the crystal field splitting Δo (10Dq) for the complex ion? Please calculate in kJ.mole-1. (c) Calculate the crystal field stabilization energy of the complex ion in kcal.mole-1 (Please neglect πe and πc energies when calculating). (Co:27, h=6.626x10-34 J.s, c=3x108 m.s-1)

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Sketch the structure of the complex in each of the follow- ing compounds and give the full compound name: (a) cis-[Co(NH3)4(H,O),](NO;)2 (b) Na,[Ru(H,O)Cl5] (c) trans-NH4[Co(C;04)2(H2O)z] (d) cis-[Ru(en);Cl2]