5.) Draw the octahedral crystal field splitting energy diagram for the following metal ions:(a) Cu²+(b) Mn2+(low- spin) (c) Fe(high-spin)(d) Co³ (high spin)

Answered: 5.) Draw the octahedral crystal field…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Please answer 22b c both.
4. Consider the following reaction: [ZnCl4]² +4 OH → [Zn(OH)4]² +4 CI If the reaction is spontaneous, then which of the following is true? (A) Chloride is a more labile ligand than hydroxide in zinc complexes (B) Hydroxide is a more labile ligand than chloride in zinc complexes (C) Chloride is a more inert ligand than hydroxide in zinc complexes (D) Hydroxide and chloride are equally labile in zinc complexes
Draw the crystal field diagram of [W(CO)6]. Determine the (a) Electronic configuration in terms t2geg (b) Number of unpaired electrons (c) Ligand field stabilization energy in terms of ΔO or ΔT
The complex ion Fe(CN)6³ is paramagnetic with one unpaired electron. The complex ion Fe(SCN)6³ has five unpaired electrons. Draw the crystal field diagrams of two complex ions. Which compound absorbs light with the shorter wavelength? Where does SCN- lie in the spectrochemical series relative to CN-? (hint: stronger or weaker 4. (a) (b) (c) field)
Circle all of the following species that exhibit geometric isomers. (a) [Rh(en)2 I2]I (b) [Pd(CO)2(CN)2](CN)2 (c) [Ni(C2O4)3]Cl4 Circle all of the following species that exhibit optical isomerism. (a) [Rh(en)2 I2]I (b) [Pd(CO)2(CN)2](CN)2 (c) [Ni(C2O4)3]Cl4
7. Which of the following complexes would most likely exhibit square planar geometry? Which would most likely exhibit tetrahedral geometry? (a) [Pt(PF:)4] (b) [Au(CN)4] (c) [Hg(CN)4]? (d) [ZrCl4] (e) [Ni(CN)4]+- (f) [Pt(CN)4]*- (5) (g) [IrCI(CO)(P(CH:);)»]
In the following list, identify a transition metal cation that cannot be used to distinguish between strong-field and weak-field ligands in octahedral complexes? (A) Cr3+ (B) Fe3+ (C) Co3+ (D) None of them (any of them can be used)
What should happen when the concentration of chloride is increased in a solution containing hexaaquocobalt(II), [Co(H2O)6] 2+ (aq)?
(II) Write the formulas for the following coordination compounds. (a) Hexaamminecobalt(III) pentachlorocuprate(II) (b) Ammonium bis(oxalato)dinitrosylchromate(III)

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5.) Draw the octahedral crystal field splitting energy diagram for the following metal ions: (a) Cu²+ (b) Mn2+(low- spin) (c) Fe(high-spin) (d) Co³ (high spin)