Sketch how the overlap between a 1s orbital and a 2p orbital directed towards it can be expected to depend on their separation.The overlap integral between an H1s orbital and an H2p orbital directed towards it on nuclei separated by a distance R is S=(R/a0)1+(R/a0)+13(R/a0)2e-R/ao. Plot this function, and find the separation for which the overlap is a maximum.

Sketch how the overlap between a 1s orbital and a 2p orbital directed towards it can be expected to depend on their separation.The overlap integral between an H1s orbital and an H2p orbital directed towards it on nuclei separated by a distance R is S=(R/a0)1+(R/a0)+13(R/a0)2e-R/ao. Plot this function, and find the separation for which the overlap is a maximum.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter7: Molecular Structures

Section: Chapter Questions

Problem 65QRT

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Question

Sketch how the overlap between a 1s orbital and a 2p orbital directed towards it can be expected to

depend on their separation.The overlap integral between an H1s orbital and an H2p orbital directed

towards it on nuclei separated by a distance R is S=(R/a0)1+(R/a0)+13(R/a0)2e-R/ao.

Plot this function, and find the separation for which the overlap is a maximum.

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